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- W4319868656 abstract "Abstract We described a copper(II)‐catalyzed [3+2] cycloaddition of N ‐aryl‐α,β‐unsaturated nitrones with disubstituted allenoates bifurcated to prepare various [1,3]oxazino[3,2‐a]indolines and dihydropyrido[1,2‐a]indolines in moderate to excellent yields. Mechanistic studies revealed that [1,3]oxazino[3,2‐a]indoline was a kinetically favored product and dihydropyrido[1,2‐a]indoline was thermodynamically favored product. Moreover, the reaction was easily performed at gram scales and chiral dihydropyrido[1,2‐a]indoline could be obtained by using chiral auxiliary. The present method highlights broad substrate scope, good functional group tolerance, and diversity of indoline scaffolds with high diastereoselectivity. magnified image" @default.
- W4319868656 created "2023-02-11" @default.
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- W4319868656 date "2023-02-21" @default.
- W4319868656 modified "2023-10-16" @default.
- W4319868656 title "Copper(II)‐Catalyzed Cascade Reactions of <i>N</i>‐Aryl Nitrones and Disubstituted Allenoates to Prepare [1,3]Oxazino[3,2‐a]indolines and Dihydropyrido[1,2‐a]indolines" @default.
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- W4319868656 doi "https://doi.org/10.1002/adsc.202201403" @default.
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