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- W4319873790 abstract "Introduction of a fluorine-containing block into block copolymers is an effective method to tune block copolymer nanoassemblies with a microphase-separated structure. However, this microphase-separated structure is difficult to clearly observe due to its nanoscale size. In this work, fluorine-containing ABC triblock copolymer vesicles of poly(ethylene glycol)-block-polystyrene-block-poly(4-vinylbenzyl pentafluorophenyl ether) (PEG-b-PS-b-PVBFP) are synthesized by reversible addition-fragmentation chain transfer (RAFT) polymerization under dispersed condition. Owing to the choice of a suitable degree of polymerization of the three blocks, the synthesized PEG45-b-PS197-b-PVBFP233 vesicles have a relatively large size of around 216 nm and a thin vesicular membrane with a thickness of around 28 nm. Ascribed to the relatively large size of the vesicles and the thin vesicular membrane, it is concluded that the fluorine-containing PVBFP block forms 9 nm columnar microdomains shielded by the PS phase in the vesicular membrane." @default.
- W4319873790 created "2023-02-11" @default.
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- W4319873790 date "2023-02-10" @default.
- W4319873790 modified "2023-09-27" @default.
- W4319873790 title "Fluorine-Containing Triblock Copolymer Vesicles with Microphase-Separated Structure" @default.
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- W4319873790 doi "https://doi.org/10.1021/acs.langmuir.2c03114" @default.
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