Matches in SemOpenAlex for { <https://semopenalex.org/work/W4319944265> ?p ?o ?g. }
- W4319944265 endingPage "125765" @default.
- W4319944265 startingPage "125765" @default.
- W4319944265 abstract "The accurate and convenient characterization of the interfacial layer is a crucial prerequisite for understanding the relationship between structure and macroscopic properties in polymer nanocomposites (PNCs). Herein, enthalpy relaxation and interfacial layer properties estimated from temperature-modulated differential scanning calorimetry (TMDSC) and broadband dielectric spectroscopy (BDS) of model PNCs with attractive interactions are investigated. We demonstrate that enthalpy relaxation enables the accurate quantification of the volume fraction of the interfacial layer (φint) as TMDSC and BDS. The parameter (χint) corresponding to the decreased degree of enthalpy hysteresis (ΔHR) related to the contribution of the interfacial layer, is identical with φint estimated from BDS, while presents only similar dependence on nanoparticle loading with φint estimated from TMDSC. This interesting phenomenon can be ascribed to the consistency between enthalpy and dielectric relaxation, which both characterize the dynamic change of polymer mainly originating from segmental relaxation. Such an unexpected correlation between enthalpy and dielectric relaxation provides a new approach to characterize the interfacial layer properties of PNCs and understand its impact on the glass transition behavior." @default.
- W4319944265 created "2023-02-11" @default.
- W4319944265 creator A5023764890 @default.
- W4319944265 creator A5032902004 @default.
- W4319944265 creator A5059900841 @default.
- W4319944265 date "2023-03-01" @default.
- W4319944265 modified "2023-10-16" @default.
- W4319944265 title "Rationalizing the interfacial layer in polymer nanocomposites: Correlation between enthalpy and dielectric relaxation" @default.
- W4319944265 cites W1971318238 @default.
- W4319944265 cites W1982193100 @default.
- W4319944265 cites W1998201069 @default.
- W4319944265 cites W2008342341 @default.
- W4319944265 cites W2010679382 @default.
- W4319944265 cites W2030656139 @default.
- W4319944265 cites W2038502132 @default.
- W4319944265 cites W2043821000 @default.
- W4319944265 cites W2045547643 @default.
- W4319944265 cites W2052465035 @default.
- W4319944265 cites W2067897825 @default.
- W4319944265 cites W2070444828 @default.
- W4319944265 cites W2073040940 @default.
- W4319944265 cites W2088654232 @default.
- W4319944265 cites W2121781332 @default.
- W4319944265 cites W2149716116 @default.
- W4319944265 cites W2157242092 @default.
- W4319944265 cites W2257909836 @default.
- W4319944265 cites W2260109794 @default.
- W4319944265 cites W2271149962 @default.
- W4319944265 cites W2290517140 @default.
- W4319944265 cites W2321698634 @default.
- W4319944265 cites W2321947895 @default.
- W4319944265 cites W2326744539 @default.
- W4319944265 cites W2327670608 @default.
- W4319944265 cites W2331563203 @default.
- W4319944265 cites W2335427976 @default.
- W4319944265 cites W2339538625 @default.
- W4319944265 cites W2400424484 @default.
- W4319944265 cites W2470438910 @default.
- W4319944265 cites W2523426736 @default.
- W4319944265 cites W2564312969 @default.
- W4319944265 cites W2570285712 @default.
- W4319944265 cites W2570959551 @default.
- W4319944265 cites W2580910706 @default.
- W4319944265 cites W2588409301 @default.
- W4319944265 cites W2598241656 @default.
- W4319944265 cites W2603245071 @default.
- W4319944265 cites W2668655778 @default.
- W4319944265 cites W2742033478 @default.
- W4319944265 cites W2802406879 @default.
- W4319944265 cites W2884715502 @default.
- W4319944265 cites W2885224565 @default.
- W4319944265 cites W2890997073 @default.
- W4319944265 cites W2891420849 @default.
- W4319944265 cites W2908721137 @default.
- W4319944265 cites W2912519761 @default.
- W4319944265 cites W2915116936 @default.
- W4319944265 cites W2929279422 @default.
- W4319944265 cites W2940840321 @default.
- W4319944265 cites W2972683796 @default.
- W4319944265 cites W2976748593 @default.
- W4319944265 cites W2986627742 @default.
- W4319944265 cites W2997103642 @default.
- W4319944265 cites W3010009594 @default.
- W4319944265 cites W3013639288 @default.
- W4319944265 cites W3015379901 @default.
- W4319944265 cites W3022294701 @default.
- W4319944265 cites W3032186458 @default.
- W4319944265 cites W3033043440 @default.
- W4319944265 cites W3037130509 @default.
- W4319944265 cites W3048586081 @default.
- W4319944265 cites W3085056995 @default.
- W4319944265 cites W3088132236 @default.
- W4319944265 cites W3100477867 @default.
- W4319944265 cites W3113343472 @default.
- W4319944265 cites W3120314627 @default.
- W4319944265 cites W3124039859 @default.
- W4319944265 cites W3138385200 @default.
- W4319944265 cites W3164091739 @default.
- W4319944265 cites W3166202064 @default.
- W4319944265 cites W3166546726 @default.
- W4319944265 cites W3167883175 @default.
- W4319944265 cites W3169650279 @default.
- W4319944265 cites W3171704969 @default.
- W4319944265 cites W3171724956 @default.
- W4319944265 cites W3180204313 @default.
- W4319944265 cites W3211775168 @default.
- W4319944265 cites W4200395710 @default.
- W4319944265 cites W4200428830 @default.
- W4319944265 cites W4210750143 @default.
- W4319944265 cites W4234216966 @default.
- W4319944265 cites W4256297049 @default.
- W4319944265 cites W4283399552 @default.
- W4319944265 cites W4375188382 @default.
- W4319944265 doi "https://doi.org/10.1016/j.polymer.2023.125765" @default.
- W4319944265 hasPublicationYear "2023" @default.
- W4319944265 type Work @default.
- W4319944265 citedByCount "1" @default.
- W4319944265 countsByYear W43199442652023 @default.