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- W4319965057 abstract "Abstract Co‐Salox complexes are suitable catalysts for the reduction of prochiral α,β‐unsaturated esters. These ligands can be prepared in a single step from available and inexpensive materials, thus representing an easily accessible alternative to previously reported Co‐catalysts. NaBH 4 is employed as reducing agent in the presence of EtOH as proton source, leading to the stereoselective formation of chiral esters, amides, and nitriles in up to 99 % yield and 96.5 : 3.5 er . The concentration of the reductant counter cation (Na + ) and the solvent polarity have been shown to correlate with reactivity and enantioselectivity, suggesting that a relatively complex mechanistic manifold is in place." @default.
- W4319965057 created "2023-02-11" @default.
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- W4319965057 date "2023-02-28" @default.
- W4319965057 modified "2023-10-18" @default.
- W4319965057 title "Co(Salox)‐Catalyzed Enantioselective Reduction of α,β‐Unsaturated Esters" @default.
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- W4319965057 doi "https://doi.org/10.1002/ejoc.202201492" @default.
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