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- W4319997777 abstract "Aryl cyclopropane represents an interesting class of cyclopropanes with relatively underexplored synthetic potential. Herein, we present a photoredox-catalyzed remote difunctionalization of aryl cyclopropanes, which enables facile construction of structurally diverse 1,3/1,5-dioxygenation products. Either alcohol or simply water is used as a nucleophile. This protocol demonstrates aryl radical cation-induced remote activation occurring via intramolecular electronic interaction spanning a cyclopropane-embedded π-conjugated system. By merging photoredox catalysis with copper(II)-mediated radical elaboration, a formal radical-polar crossover manifold is realized. Moreover, this reaction features mild conditions, a wide substrate scope, good functional group tolerance, and high regioselectivities. Preliminary mechanistic experiments probe the radical-involved process, indicating a concerted SN2-like ring-opening functionalization." @default.
- W4319997777 created "2023-02-11" @default.
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- W4319997777 date "2023-01-01" @default.
- W4319997777 modified "2023-10-16" @default.
- W4319997777 title "Aryl radical cation promoted remote dioxygenation of cyclopropane derivatives" @default.
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- W4319997777 doi "https://doi.org/10.1016/j.xcrp.2022.101233" @default.
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