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• W4319997967 abstract "Chiral borates can undergo various transformations that occur with high stereospecificity, so they are of great significance in asymmetric synthesis. Herein we described a new catalytic system for copper-catalyzed asymmetric conjugate hydroboration of α,β-unsaturated amides. Under the optimal conditions, the reactions proceeded smoothly to afford the corresponding chiral β-hydroxyl amides with up to 96% yield and 84% ee by employing chiral N,P-ligand. The reaction conditions are mild, the operation is simple, and it has good substrate generality." @default.
• W4319997967 created "2023-02-11" @default.
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• W4319997967 date "2023-03-01" @default.
• W4319997967 modified "2023-10-18" @default.
• W4319997967 title "Copper-catalyzed enantioselective 1,4-hydroboration of α,β-unsaturated amides" @default.
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• W4319997967 doi "https://doi.org/10.1016/j.tetlet.2023.154364" @default.
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