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- W4320032645 abstract "The synthesis and structure analysis of a series of mono and diylide-substituted tetrylenes of type YEX and Y2 E (E=Ge, Sn, Pb; X=Cl or Br) using a thiophosphinoyl-tethered metallated ylide (Y=Ph2 P(S)-C-P(pip)Ph2 with pip=piperidyl) is reported, amongst the first ylide-substituted plumbylenes. The tetrylenes feature distinct trends in the spectroscopic and structural properties of the ylide ligand with increasing atomic number of the tetrel element. For instance, an increasingly high-field shifted signal for the thiophosphinoyl group is observed in the 31 P{1 H} NMR spectrum as a consequence of the increasing polarity of the element-carbon bond, which likewise results in a shortening of the ylidic C-P bond in the solid-state structure. The diylidyltetrylenes are unstable towards transylidation forming the mono(ylide)tetrylenes when treated with the tetrel dihalides according to the stability trend: Y2 Pb<Y2 Sn<Y2 Ge<YPbBr<YSnCl<YGeCl. Starting from the monoylide-substituted chlorotertrylenes the first unsymmetrical diylidyltetrylenes of type YEY' can be accessed, whose solid-state structures revealed that not the C-E but the S-E bond to the thiophosphinoyl group is most affected by the second ylide substituent." @default.
- W4320032645 created "2023-02-12" @default.
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- W4320032645 date "2023-03-17" @default.
- W4320032645 modified "2023-10-06" @default.
- W4320032645 title "Thiophosphinoyl‐Tethered Ylide‐Substituted Heavier Carbenes: Synthesis, Structures and Stabilities" @default.
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- W4320032645 doi "https://doi.org/10.1002/chem.202203863" @default.
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