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- W4320032787 abstract "Incorporating photo-switches into skeletal structures of microporous materials or as guest molecules yield photo-responsive materials for low-energy CO2 capture but at the expense of lower CO2 uptake. Here, we overcome this limitation by exploiting trans-cis photoisomerization of azobenzene loaded into the micropores of hypercross-linked polymers (HCPs) derived from waste polystyrene. Azobenzene in HCP pores reduced CO2 uptake by 19 %, reaching 37.7 cm3 g-1 , but this loss in CO2 uptake was not only recovered by trans-cis photoisomerization of azobenzene, but also increased by 22 %, reaching 56.9 cm3 g-1 , when compared to as-prepared HCPs. Computational simulations show that this increase in CO2 uptake is due to photo-controlled increments in 10-20 Å micropore volume, i. e., adsorption sites and a photo-reversible positive dipole moment. Irradiating these HCPs with visual-range light reverted CO2 uptake to 33 cm3 g-1 . This shows that it is feasible to recycle waste polystyrene into advanced materials for low-energy carbon capture." @default.
- W4320032787 created "2023-02-12" @default.
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- W4320032787 date "2023-03-23" @default.
- W4320032787 modified "2023-10-17" @default.
- W4320032787 title "Photo‐Modulating CO<sub>2</sub> Uptake of Hypercross‐linked Polymers Upcycled from Polystyrene Waste" @default.
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- W4320032787 doi "https://doi.org/10.1002/cssc.202300019" @default.
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