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• W4320481189 abstract "Achieving the long-lived and strong room-temperature phosphorescence (RTP) is challengeable but desirable, especially for the enhanced phosphorescence and metal-free nanomaterials. Herein, we initially synthesized the green-fluorescence carbon dots (pm-CDs), and further obtained the composite of [email protected] with a long RTP lifetime of 1.01 s through embedding pm-CDs in dicyandiamide (DCDA). And the bright and long-lived afterglow of [email protected] with 365 nm of UV light excitation was observed by the naked eyes for more than 17 s either emerging as the dry solid or in water. Importantly, the phosphorescence intensity and lifetime of [email protected] were remarkably promoted owing to the intermolecular hydrogen bonds and the rigid environment, hence facilitating the intersystem crossing (ISC) process and restricting the non-radiative transition of triplet excitons. Taking advantage of the superior solid-state luminescence of [email protected], we further innovatively prepared the white light-emitting diodes (WLEDs) with the tunable color temperatures by regulating the mass of [email protected] coated on the chips. This proposed study originally employed DCDA as a matrix to separate and immobilize pm-CDs, which built up a new avenue to improve the RTP property and offered a promising application in WLEDs." @default.
• W4320481189 created "2023-02-14" @default.
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• W4320481189 date "2023-06-01" @default.
• W4320481189 modified "2023-09-30" @default.
• W4320481189 title "Hydrogen bonds and space restriction promoting long-lived room-temperature phosphorescence and its application for white light-emitting diodes" @default.
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• W4320481189 doi "https://doi.org/10.1016/j.jcis.2023.02.040" @default.
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