FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4320483414> ?p ?o ?g. }

• W4320483414 endingPage "2523" @default.
• W4320483414 startingPage "2515" @default.
• W4320483414 abstract "High-conductivity solid electrolytes, such as the Na superionic conductor, NaSICON, are poised to play an increasingly important role in safe, reliable battery-based energy storage, enabling advanced sodium-based batteries. Coupled demands of increased current density (≥0.1 A cm–2) and low-temperature (<200 °C) operation, combined with increased discharge times for long-duration storage (>12 h), challenge the limitations of solid electrolytes. Here, we explore the penetration of molten sodium into NaSICON at high current densities. Previous studies of β″-alumina proposed that Poiseuille pressure-driven cracking (mode I) and recombination of ions and electrons within the solid electrolyte (mode II) are the two main mechanisms for Na penetration, but a comprehensive study of Na penetration in NaSICON is necessary, particularly at high current density. To further understand these modes, this work employs unidirectional galvanostatic testing of Na|NaSICON|Na symmetric cells at 0.1 A cm–2 over 23 h at 110 °C. While galvanostatic testing shows a relatively constant yet increasingly noisy voltage profile, electrochemical impedance spectroscopy (EIS) reveals a significant decrease in cell impedance correlated with significant sodium penetration, as observed in scanning electron microscopy (SEM). Further SEM analysis of sodium accumulation within NaSICON suggests that mode II failure may be far more prevalent than previously considered. Further, these findings suggest that total (dis)charge density (mAh cm–2), as opposed to current density (mA cm–2), may be a more critical parameter when examining solid electrolyte failure, highlighting the challenge of achieving long discharge times in batteries using solid electrolytes. Together, these results provide a better understanding of the limitations of NaSICON solid electrolytes under high current and emphasize the need for improved electrode–electrolyte interfaces." @default.
• W4320483414 created "2023-02-14" @default.
• W4320483414 creator A5004874777 @default.
• W4320483414 creator A5008461103 @default.
• W4320483414 creator A5023071722 @default.
• W4320483414 creator A5042722112 @default.
• W4320483414 creator A5073967500 @default.
• W4320483414 date "2023-02-13" @default.
• W4320483414 modified "2023-09-26" @default.
• W4320483414 title "Molten Sodium Penetration in NaSICON Electrolytes at 0.1 A cm^–2" @default.
• W4320483414 cites W1673251294 @default.
• W4320483414 cites W1849487101 @default.
• W4320483414 cites W1975291670 @default.
• W4320483414 cites W1977370831 @default.
• W4320483414 cites W1996879303 @default.
• W4320483414 cites W2012678971 @default.
• W4320483414 cites W2021200699 @default.
• W4320483414 cites W2030147340 @default.
• W4320483414 cites W2039080910 @default.
• W4320483414 cites W2055623248 @default.
• W4320483414 cites W2068945150 @default.
• W4320483414 cites W2074278890 @default.
• W4320483414 cites W2077807876 @default.
• W4320483414 cites W2089204569 @default.
• W4320483414 cites W2167639276 @default.
• W4320483414 cites W2179139031 @default.
• W4320483414 cites W227761974 @default.
• W4320483414 cites W2326096023 @default.
• W4320483414 cites W2341894171 @default.
• W4320483414 cites W2415166295 @default.
• W4320483414 cites W2508700492 @default.
• W4320483414 cites W2522104499 @default.
• W4320483414 cites W2527310226 @default.
• W4320483414 cites W2531515086 @default.
• W4320483414 cites W2551057468 @default.
• W4320483414 cites W2561998267 @default.
• W4320483414 cites W2570193059 @default.
• W4320483414 cites W2600615905 @default.
• W4320483414 cites W2725925537 @default.
• W4320483414 cites W2731645694 @default.
• W4320483414 cites W2741638086 @default.
• W4320483414 cites W2762979234 @default.
• W4320483414 cites W2765147628 @default.
• W4320483414 cites W2795226759 @default.
• W4320483414 cites W2892109456 @default.
• W4320483414 cites W2896132928 @default.
• W4320483414 cites W2901936736 @default.
• W4320483414 cites W2907588123 @default.
• W4320483414 cites W2921869224 @default.
• W4320483414 cites W2956006083 @default.
• W4320483414 cites W2964528467 @default.
• W4320483414 cites W2973696246 @default.
• W4320483414 cites W2984942060 @default.
• W4320483414 cites W3005325433 @default.
• W4320483414 cites W3009604216 @default.
• W4320483414 cites W3031546475 @default.
• W4320483414 cites W3047303673 @default.
• W4320483414 cites W3082520047 @default.
• W4320483414 cites W3092590267 @default.
• W4320483414 cites W3096155006 @default.
• W4320483414 cites W3101655375 @default.
• W4320483414 cites W3104327699 @default.
• W4320483414 cites W3131490378 @default.
• W4320483414 cites W3163619474 @default.
• W4320483414 cites W3164048729 @default.
• W4320483414 cites W3186415760 @default.
• W4320483414 cites W3196366450 @default.
• W4320483414 cites W3198704086 @default.
• W4320483414 cites W3199039666 @default.
• W4320483414 cites W4200180090 @default.
• W4320483414 cites W4282928689 @default.
• W4320483414 cites W4284880204 @default.
• W4320483414 cites W4296187463 @default.
• W4320483414 doi "https://doi.org/10.1021/acsaem.2c03944" @default.
• W4320483414 hasPublicationYear "2023" @default.
• W4320483414 type Work @default.
• W4320483414 citedByCount "0" @default.
• W4320483414 crossrefType "journal-article" @default.
• W4320483414 hasAuthorship W4320483414A5004874777 @default.
• W4320483414 hasAuthorship W4320483414A5008461103 @default.
• W4320483414 hasAuthorship W4320483414A5023071722 @default.
• W4320483414 hasAuthorship W4320483414A5042722112 @default.
• W4320483414 hasAuthorship W4320483414A5073967500 @default.
• W4320483414 hasConcept C109883240 @default.
• W4320483414 hasConcept C113196181 @default.
• W4320483414 hasConcept C121332964 @default.
• W4320483414 hasConcept C131540310 @default.
• W4320483414 hasConcept C147789679 @default.
• W4320483414 hasConcept C17525397 @default.
• W4320483414 hasConcept C185592680 @default.
• W4320483414 hasConcept C191897082 @default.
• W4320483414 hasConcept C192562407 @default.
• W4320483414 hasConcept C207740977 @default.
• W4320483414 hasConcept C43617362 @default.
• W4320483414 hasConcept C52859227 @default.
• W4320483414 hasConcept C537181965 @default.
• W4320483414 hasConcept C62520636 @default.
• W4320483414 hasConcept C68801617 @default.

• next