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- W4320485563 abstract "We report in situ generation of a 6,6′-biindeno[1,2-b]anthracene (BIA) derivative as an open-shell biaryl with high diradical character, which could be identified by mass spectrometry, NMR spectroscopy, single-crystal X-ray analysis, UV–vis–NIR absorption spectroscopy, and electron paramagnetic resonance (EPR) spectroscopy. Theoretical calculations by various methods and variable-temperature EPR analyses were performed to tackle the elusive ground state of BIA diradical, suggesting a singlet ground state with a nearly degenerate triplet state. These results provide insight into the design of unique open-shell biaryls." @default.
- W4320485563 created "2023-02-14" @default.
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- W4320485563 date "2023-02-13" @default.
- W4320485563 modified "2023-10-18" @default.
- W4320485563 title "6,6′-Biindeno[1,2-<i>b</i>]anthracene: An Open-Shell Biaryl with High Diradical Character" @default.
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- W4320485563 doi "https://doi.org/10.1021/jacs.2c13890" @default.
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