Matches in SemOpenAlex for { <https://semopenalex.org/work/W4320487108> ?p ?o ?g. }
- W4320487108 endingPage "122465" @default.
- W4320487108 startingPage "122465" @default.
- W4320487108 abstract "The photoelectrocatalytic (PEC) valorization of glycerol is emerging for the co-generation of hydrogen and value-added organics like glyceraldehyde (GAD) or dihydroxyacetone (DHA). In this work, we have designed, tested and optimized a pioneering photoelectrolyser with a non-noble metal-based photoanode (WO3), operating in near-neutral conditions and using a proton-exchange membrane (PEM) which ensures the elution of a purified hydrogen stream from the cathode side while selectively oxidizing glycerol on the anode. The influence of light irradiation, external bias and cell temperature has been investigated, leading to GAD and DHA production rates of 11.1 and 5.2 mmol m−2 h−1 at 60 ºC and 1.2 V, along with 44.0 mmol H2 m−2 h−1. The long-term stability of the photoelectrolyser has also been validated and the particularities of this system with respect to other conventional devices have been discussed. PEC stands as a promising sustainable technology for the simultaneous H2 generation and biomass valorization." @default.
- W4320487108 created "2023-02-14" @default.
- W4320487108 creator A5015916954 @default.
- W4320487108 creator A5022845740 @default.
- W4320487108 creator A5024842706 @default.
- W4320487108 creator A5052954357 @default.
- W4320487108 creator A5056690555 @default.
- W4320487108 creator A5068817497 @default.
- W4320487108 creator A5076532813 @default.
- W4320487108 date "2023-06-01" @default.
- W4320487108 modified "2023-10-14" @default.
- W4320487108 title "First PEM photoelectrolyser for the simultaneous selective glycerol valorization into value-added chemicals and hydrogen generation" @default.
- W4320487108 cites W1996849369 @default.
- W4320487108 cites W2005164040 @default.
- W4320487108 cites W2013102317 @default.
- W4320487108 cites W2017295803 @default.
- W4320487108 cites W2018525635 @default.
- W4320487108 cites W2038325495 @default.
- W4320487108 cites W2038788803 @default.
- W4320487108 cites W2041229739 @default.
- W4320487108 cites W2061252359 @default.
- W4320487108 cites W2064392372 @default.
- W4320487108 cites W2084217486 @default.
- W4320487108 cites W2084557418 @default.
- W4320487108 cites W2109370776 @default.
- W4320487108 cites W2114061607 @default.
- W4320487108 cites W2114352247 @default.
- W4320487108 cites W2133329106 @default.
- W4320487108 cites W2136560140 @default.
- W4320487108 cites W2161627019 @default.
- W4320487108 cites W228825672 @default.
- W4320487108 cites W2303134598 @default.
- W4320487108 cites W2317825609 @default.
- W4320487108 cites W2356407698 @default.
- W4320487108 cites W2428060906 @default.
- W4320487108 cites W2461085004 @default.
- W4320487108 cites W2479480771 @default.
- W4320487108 cites W2483314746 @default.
- W4320487108 cites W2506142827 @default.
- W4320487108 cites W2512164950 @default.
- W4320487108 cites W2561031873 @default.
- W4320487108 cites W2590855502 @default.
- W4320487108 cites W2600729851 @default.
- W4320487108 cites W2601707571 @default.
- W4320487108 cites W2604601039 @default.
- W4320487108 cites W2618914183 @default.
- W4320487108 cites W2774636363 @default.
- W4320487108 cites W2788537664 @default.
- W4320487108 cites W2799562744 @default.
- W4320487108 cites W2802379004 @default.
- W4320487108 cites W2806143680 @default.
- W4320487108 cites W2897800652 @default.
- W4320487108 cites W2903565322 @default.
- W4320487108 cites W2924619279 @default.
- W4320487108 cites W2943623443 @default.
- W4320487108 cites W2965483942 @default.
- W4320487108 cites W2969286001 @default.
- W4320487108 cites W2973172499 @default.
- W4320487108 cites W2975445969 @default.
- W4320487108 cites W2988554781 @default.
- W4320487108 cites W3011269056 @default.
- W4320487108 cites W3011290112 @default.
- W4320487108 cites W3015717209 @default.
- W4320487108 cites W3035960708 @default.
- W4320487108 cites W3041811855 @default.
- W4320487108 cites W3042890672 @default.
- W4320487108 cites W3047252455 @default.
- W4320487108 cites W3047845517 @default.
- W4320487108 cites W3085617819 @default.
- W4320487108 cites W3087495587 @default.
- W4320487108 cites W3094091113 @default.
- W4320487108 cites W3117528154 @default.
- W4320487108 cites W3118291082 @default.
- W4320487108 cites W3119938347 @default.
- W4320487108 cites W3126392329 @default.
- W4320487108 cites W3130551943 @default.
- W4320487108 cites W3131056231 @default.
- W4320487108 cites W3136937018 @default.
- W4320487108 cites W3163182738 @default.
- W4320487108 cites W3163885877 @default.
- W4320487108 cites W3171827613 @default.
- W4320487108 cites W3193499453 @default.
- W4320487108 cites W3195267759 @default.
- W4320487108 cites W3202686196 @default.
- W4320487108 cites W4205191650 @default.
- W4320487108 cites W4206306325 @default.
- W4320487108 cites W4207073729 @default.
- W4320487108 cites W4214745367 @default.
- W4320487108 cites W4220721694 @default.
- W4320487108 cites W4221039884 @default.
- W4320487108 cites W4223512304 @default.
- W4320487108 cites W4226448829 @default.
- W4320487108 cites W4290860478 @default.
- W4320487108 doi "https://doi.org/10.1016/j.apcatb.2023.122465" @default.
- W4320487108 hasPublicationYear "2023" @default.
- W4320487108 type Work @default.
- W4320487108 citedByCount "2" @default.
- W4320487108 countsByYear W43204871082023 @default.