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- W4320857481 abstract "Two novel arsenotungstate species, [As4W48O168]36– (1a) and [As2W21O77(H2O)3]22– (2a), have been successfully isolated under a one-pot synthetic method. 1a is the second largest arsenotungstate cluster and is constructed from four {AsW12} clusters combined together. 2a can be described as lacunary sites of {As2W19} filled by {W2O8} units. Compounds 1 and 2 exhibit proton conductivity properties, and the conductivity value of 1 is 5.0 × 10–3 S cm–1 at 98% relative humidity and 75 °C. This work proves that the lattice water molecules and polyoxoanions can participate in the formation of a hydrogen bond, acting as effective pathway for intermolecular proton conduction." @default.
- W4320857481 created "2023-02-16" @default.
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- W4320857481 date "2023-02-15" @default.
- W4320857481 modified "2023-10-11" @default.
- W4320857481 title "Discovery and Isolation of Two Arsenotungastate Species: [As<sub>4</sub>W<sub>48</sub>O<sub>168</sub>]<sup>36–</sup> and [As<sub>2</sub>W<sub>21</sub>O<sub>77</sub>(H<sub>2</sub>O)<sub>3</sub>]<sup>22–</sup>" @default.
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- W4320857481 doi "https://doi.org/10.1021/acs.inorgchem.2c04280" @default.
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