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- W4320857523 abstract "Herein, we report a one-pot, chemoenzymatic process for the synthesis of enantioenriched C(1)-allylated tetrahydroisoquinolines. This transformation couples a monoamine oxidase (MAO-N)-catalyzed oxidation with a metal catalyzed allylboration, followed by a biocatalytic deracemization to afford allylic amine derivatives in both high yields and good to high enantiomeric excess. The cascade is operationally simple, with all components added at the start of the reaction and can be used to generate key building blocks for further elaboration." @default.
- W4320857523 created "2023-02-16" @default.
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- W4320857523 date "2023-02-15" @default.
- W4320857523 modified "2023-09-25" @default.
- W4320857523 title "One-Pot Chemoenzymatic Cascade for the Enantioselective C(1)-Allylation of Tetrahydroisoquinolines" @default.
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- W4320857523 doi "https://doi.org/10.1021/jacs.2c09176" @default.
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