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- W4320921258 endingPage "122642" @default.
- W4320921258 startingPage "122642" @default.
- W4320921258 abstract "Various ruthenium-incorporated tris- and bishomocubane analogues have been documented. The reaction between [Cp*RuCl2]2 (Cp* = η5-C5Me5) and [BH2Se3]Li at room temperature yielded bimetallic trishomocubane, [(Cp*Ru)2(μ3-Se)4(μ-Se)3(BH)2], 1; and bishomocubane, [(Cp*Ru)2(μ3-Se)5(μ-Se)2(BH)], 2. To the best of our knowledge, compound 1 is the first Se analogue of trishomocubane that has been isolated as a 1,2,3-isomer. With an objective of replacing the B–H vertex of compound 2 with an isolobal {Fe(CO)3} fragment, the reaction of compound 2 with [Fe2(CO)9] was carried out under photolytic conditions. Although the aim of obtaining a homocubane core compound was not achieved, the reaction yielded interesting heterometallic chalcogenide compounds, [{μ-Se(Cp*Ru(CO)2)}2{Fe(CO)3}4(μ4-Se)], 3, and [{Cp*Ru(CO)2}(μ4-Se){(μ-H)(Fe(CO)3)3}], 4. Compound 3 is a unique example of vertex-fused cluster, in which two butterfly {Fe2Se2} moieties are fused together through a common Se vertex and a {Cp*Ru(CO)2} unit is attached to each of the terminal Se atoms. In compound 4, the Se atom of a {Fe3Se} tetrahedron is connected to a {Cp*Ru(CO)2} fragment. Multinuclear NMR, infrared and UV–Vis spectroscopy, mass spectrometry as well as single crystal X-ray diffraction studies were performed for the characterization of compounds 1–4. Density functional theory methods were also employed for elucidating the bonding in these compounds." @default.
- W4320921258 created "2023-02-16" @default.
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- W4320921258 date "2023-04-01" @default.
- W4320921258 modified "2023-10-17" @default.
- W4320921258 title "Synthesis and chemistry of Ru-bimetallic homocubane clusters" @default.
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- W4320921258 doi "https://doi.org/10.1016/j.jorganchem.2023.122642" @default.
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