Matches in SemOpenAlex for { <https://semopenalex.org/work/W4320921873> ?p ?o ?g. }
- W4320921873 endingPage "1797" @default.
- W4320921873 startingPage "1797" @default.
- W4320921873 abstract "Epoxides are essential precursors for epoxy resins and other chemical products. In this study, we investigated whether electrochemically oxidizing carbonate ions could produce percarbonate to promote an epoxidation reaction in the presence of appropriate metal catalysts, although Tanaka and co-workers had already completed a separate study in which the electrochemical oxidation of chloride ions was used to produce hypochlorite ions for electrochemical epoxidation. We found that epoxides could be obtained from styrene derivatives in the presence of metal complexes, including manganese(III) and oxidovanadium(IV) porphyrin complexes and manganese salen complexes, using a boron-doped diamond as the anode. After considering various complexes as potential catalysts, we found that manganese salen complexes showed better performance in terms of epoxide yield. Furthermore, the substituent effect of the manganese salen complex was also investigated, and it was found that the highest epoxide yields were obtained when Jacobsen’s catalyst was used. Although there is still room for improving the yields, this study has shown that the in situ electrochemical generation of percarbonate ions is a promising method for the electrochemical epoxidation of alkenes." @default.
- W4320921873 created "2023-02-16" @default.
- W4320921873 creator A5001307394 @default.
- W4320921873 creator A5006608503 @default.
- W4320921873 creator A5017125020 @default.
- W4320921873 creator A5057480276 @default.
- W4320921873 creator A5057552801 @default.
- W4320921873 creator A5069902972 @default.
- W4320921873 creator A5090792146 @default.
- W4320921873 date "2023-02-14" @default.
- W4320921873 modified "2023-10-16" @default.
- W4320921873 title "Electrochemical Epoxidation Catalyzed by Manganese Salen Complex and Carbonate with Boron-Doped Diamond Electrode" @default.
- W4320921873 cites W1963729490 @default.
- W4320921873 cites W1969024947 @default.
- W4320921873 cites W1983244152 @default.
- W4320921873 cites W1984133498 @default.
- W4320921873 cites W1985215044 @default.
- W4320921873 cites W1998829257 @default.
- W4320921873 cites W2002508888 @default.
- W4320921873 cites W2006101043 @default.
- W4320921873 cites W2009637509 @default.
- W4320921873 cites W2011412061 @default.
- W4320921873 cites W2014643939 @default.
- W4320921873 cites W2014865578 @default.
- W4320921873 cites W2039318499 @default.
- W4320921873 cites W2044649112 @default.
- W4320921873 cites W2047104246 @default.
- W4320921873 cites W2048848302 @default.
- W4320921873 cites W2052345066 @default.
- W4320921873 cites W2054635745 @default.
- W4320921873 cites W2060297444 @default.
- W4320921873 cites W2070691881 @default.
- W4320921873 cites W2078324730 @default.
- W4320921873 cites W2079160379 @default.
- W4320921873 cites W2079594551 @default.
- W4320921873 cites W2091541514 @default.
- W4320921873 cites W2094211547 @default.
- W4320921873 cites W2109082447 @default.
- W4320921873 cites W2127527817 @default.
- W4320921873 cites W2128259531 @default.
- W4320921873 cites W2135029613 @default.
- W4320921873 cites W2137619211 @default.
- W4320921873 cites W2261666840 @default.
- W4320921873 cites W2329922102 @default.
- W4320921873 cites W2332540986 @default.
- W4320921873 cites W2403779210 @default.
- W4320921873 cites W2507254547 @default.
- W4320921873 cites W2549866776 @default.
- W4320921873 cites W2581387791 @default.
- W4320921873 cites W2608722364 @default.
- W4320921873 cites W2669296884 @default.
- W4320921873 cites W2752579916 @default.
- W4320921873 cites W2761551323 @default.
- W4320921873 cites W2896360139 @default.
- W4320921873 cites W2916372682 @default.
- W4320921873 cites W2939245395 @default.
- W4320921873 cites W2985607578 @default.
- W4320921873 cites W2997145755 @default.
- W4320921873 cites W3012179193 @default.
- W4320921873 cites W3113530141 @default.
- W4320921873 cites W3164483471 @default.
- W4320921873 cites W3167388618 @default.
- W4320921873 cites W3181627839 @default.
- W4320921873 cites W4224223197 @default.
- W4320921873 cites W4253816275 @default.
- W4320921873 cites W4282050286 @default.
- W4320921873 doi "https://doi.org/10.3390/molecules28041797" @default.
- W4320921873 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36838783" @default.
- W4320921873 hasPublicationYear "2023" @default.
- W4320921873 type Work @default.
- W4320921873 citedByCount "0" @default.
- W4320921873 crossrefType "journal-article" @default.
- W4320921873 hasAuthorship W4320921873A5001307394 @default.
- W4320921873 hasAuthorship W4320921873A5006608503 @default.
- W4320921873 hasAuthorship W4320921873A5017125020 @default.
- W4320921873 hasAuthorship W4320921873A5057480276 @default.
- W4320921873 hasAuthorship W4320921873A5057552801 @default.
- W4320921873 hasAuthorship W4320921873A5069902972 @default.
- W4320921873 hasAuthorship W4320921873A5090792146 @default.
- W4320921873 hasBestOaLocation W43209218731 @default.
- W4320921873 hasConcept C147789679 @default.
- W4320921873 hasConcept C161790260 @default.
- W4320921873 hasConcept C17525397 @default.
- W4320921873 hasConcept C178790620 @default.
- W4320921873 hasConcept C179104552 @default.
- W4320921873 hasConcept C185592680 @default.
- W4320921873 hasConcept C199164860 @default.
- W4320921873 hasConcept C2776832558 @default.
- W4320921873 hasConcept C2776920199 @default.
- W4320921873 hasConcept C2778689049 @default.
- W4320921873 hasConcept C52859227 @default.
- W4320921873 hasConcept C528890316 @default.
- W4320921873 hasConcept C544153396 @default.
- W4320921873 hasConcept C77176794 @default.
- W4320921873 hasConceptScore W4320921873C147789679 @default.
- W4320921873 hasConceptScore W4320921873C161790260 @default.
- W4320921873 hasConceptScore W4320921873C17525397 @default.
- W4320921873 hasConceptScore W4320921873C178790620 @default.