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- W4321100511 abstract "Abstract Assessing the lifetimes of alloys in humid, corrosive environments requires growth kinetic information regarding individual instances of damage, e.g. pit growth rates. Corrosion rates measured at the continuum scale using mass change convolute the rate of pit nucleation and growth, providing limited information on local kinetics. The current study used in-situ X-ray computed tomography to measure growth rates of individual pits in aluminum over 100 h of exposure in a humid, chloride environment. While pits grew at relatively constant rates over the first hours after nucleation, significant growth-rate nonlinearities subsequently occurred. These were linked to both droplet spreading, which altered the cathode size, and changes in the mode of pit growth. Pit morphology appeared to influence the dominant growth mode and the duration of pit growth. Post-mortem serial sectioning revealed pits preferentially attacked grain-boundary triple junctions and dislocation boundaries." @default.
- W4321100511 created "2023-02-17" @default.
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- W4321100511 date "2023-02-16" @default.
- W4321100511 modified "2023-09-30" @default.
- W4321100511 title "The evolution of pit morphology and growth kinetics in aluminum during atmospheric corrosion" @default.
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- W4321100511 doi "https://doi.org/10.1038/s41529-023-00328-7" @default.
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