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• W4321123057 startingPage "5826" @default.
• W4321123057 abstract "Regioselective stepwise phenylation of 4,7-diarylbenzo[c][1,2,5]thiadiazole fluorophores has been achieved through a facile one-pot, three-step synthetic strategy involving sequential borylation, hydroxydechlorination and Suzuki-Miyaura cross-coupling reactions. Crucial to the selectivity was the use of BCl3 to regioselectively install a boronic acid group in the ortho-position of only one of the diaryl groups. The subsequent introduction of ortho-phenyl groups through Suzuki-Miyaura cross-coupling gave rise to twisted structures with hindered intramolecular rotation, providing a structural lever with which the fluorophore absorption and emission properties could be adjusted." @default.
• W4321123057 created "2023-02-18" @default.
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• W4321123057 date "2023-01-01" @default.
• W4321123057 modified "2023-10-18" @default.
• W4321123057 title "Regioselective electrophilic aromatic borylation as a method for synthesising sterically hindered benzothiadiazole fluorophores" @default.
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• W4321123057 doi "https://doi.org/10.1039/d2ra08319a" @default.
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