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- W4321350058 abstract "Spectroscopic study of water splitting by neutral metal clusters is crucial to understanding the microscopic mechanism of catalytic processes but has been proven to be a challenging experimental target due to the difficulty in size selection. Here, we report a size-specific infrared spectroscopic study of the reactions between neutral group 3 metals and water molecules based on threshold photoionization using a vacuum ultraviolet laser. Quantum chemical calculations were carried out to identify the structures and to assign the experimental spectra. All the M2O4H4 (M = Sc, Y, La) products are found to have the intriguing M2(μ2-O)(μ2-H)(μ2-OH)(η1-OH)2 structures, indicating that the H-OH bond breaking, the M-O/M-H/M-OH bond formation, and hydrogen production proceed efficiently in the reactions between laser-vaporized metals and water molecules. The joint experimental and theoretical results on the atomic scale demonstrate that the water splitting by neutral group 3 metals is both thermodynamically exothermic and kinetically facile in the gas phase. These findings have important implications for unravelling the structure-reactivity relationship of catalysts with isolated metal atoms/clusters dispersed on supports." @default.
- W4321350058 created "2023-02-20" @default.
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- W4321350058 date "2023-11-01" @default.
- W4321350058 modified "2023-09-26" @default.
- W4321350058 title "Spectroscopic identification of water splitting by neutral group 3 metals" @default.
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- W4321350058 doi "https://doi.org/10.1016/j.cclet.2023.108244" @default.
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