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- W4321365718 abstract "An oxidative strategy is reported to access α-oxo BMIDA gold carbenes directly from BMIDA-terminated alkynes. Besides offering expedient access to seldom studied boryl metal carbenes, these BMIDA gold carbene species undergo facile insertions into methyl, methylene, methine, and benzylic C-H bonds in the absence of the Thorpe-Ingold effect. They also undergo efficient OH insertion, cyclopropanation, and F-C alkylations. This chemistry provides rapid access to structurally diverse α-BMIDA ketones, which are scarcely documented. In combination with DFT studies, the role of BMIDA is established to be an electron-donating group that attenuates the high electrophilicity of the gold carbene center." @default.
- W4321365718 created "2023-02-21" @default.
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- W4321365718 date "2023-03-14" @default.
- W4321365718 modified "2023-10-17" @default.
- W4321365718 title "Reactivities of α‐Oxo BMIDA Gold Carbenes Generated by Gold‐Catalyzed Oxidation of BMIDA‐Terminated Alkynes" @default.
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- W4321365718 doi "https://doi.org/10.1002/anie.202218175" @default.
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