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- W4321434644 abstract "Abstract Anilines selectively arylated at their ortho, meta or para positions are useful building blocks in synthesis and have found applications in many areas. The most straightforward method for their synthesis relies on the direct arylation of a C(sp2)–H bond of anilines, an attractive strategy avoiding the prefunctionalization of the starting anilines provided that such arylations proceed with high levels of regioselectivity. Such reactions are presented and discussed, in a comprehensive manner, in this review article, with an emphasis on the regioselectivity of the processes and factors governing both the reactivity and selectivity. 1 Introduction 2 ortho-Arylation of Anilines 2.1 Direct C(sp2)–H ortho-Arylation of Anilines 2.2 Directed C(sp2)–H ortho-Arylation of Anilines 3 meta-Arylation of Anilines 4 para-Arylation of Anilines 4.1 Direct C(sp2)–H para-Arylation of Anilines via Oxidative Radical Homodimerization 4.2 Direct C(sp2)–H para-Arylation of Anilines via Transition-Metal Catalysis 5 Conclusion and Outlook" @default.
- W4321434644 created "2023-02-22" @default.
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- W4321434644 creator A5019111700 @default.
- W4321434644 creator A5042507092 @default.
- W4321434644 creator A5080965205 @default.
- W4321434644 date "2023-02-21" @default.
- W4321434644 modified "2023-09-30" @default.
- W4321434644 title "Direct Arylation of C(sp2)–H Bonds in Anilines" @default.
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- W4321434644 doi "https://doi.org/10.1055/a-2039-7985" @default.
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