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• W4321438161 abstract "Although transition metal selenides are considered to be extremely promising anode materials for lithium-ion batteries (LIBs), severe volume changes and low electronic conductivity are their huge and unavoidable challenges. To solve these problems, CoSe nanoparticles in-situ grown on the inner surface of every macropore of 3D honeycomb C is successfully synthesized by three simple steps: dense assembling of polystyrene spheres, calcination and gaseous selenylation. The sizes of CoSe and honeycomb pores are 10–15 nm and 190 nm, respectively. The content of CoSe is 72 wt%. This unique architecture guarantees high electrochemical activity, rapid reaction kinetics and excellent structural stability of CoSe, as identified by cycling and rate performance measurements, various electrochemical kinetics analyses and ex-situ characterization of the cycled electrode material. As a result, the [email protected] C anode exhibits extraordinary cycling performance (823.5 mAh g−1 after 200 cycles at 0.5 A g−1, 610.1 mAh g−1 after 250 cycles at 2 A g−1, 247 mAh g−1 after 1500 cycles at 5 A g−1) and exceptional rate capability (261.9 mAh g−1 at 10 A g−1, 1491.4 mAh g−1 at 0.1 A g−1), demonstrating that it is a potential anode material for high-performance LIBs." @default.
• W4321438161 created "2023-02-22" @default.
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• W4321438161 date "2023-06-01" @default.
• W4321438161 modified "2023-10-17" @default.
• W4321438161 title "CoSe nanoparticles in-situ grown in 3D honeycomb carbon for high-performance lithium storage" @default.
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• W4321438161 doi "https://doi.org/10.1016/j.jcis.2023.02.098" @default.
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