Matches in SemOpenAlex for { <https://semopenalex.org/work/W4321439086> ?p ?o ?g. }
- W4321439086 endingPage "122507" @default.
- W4321439086 startingPage "122507" @default.
- W4321439086 abstract "Reactive oxygen species (ROS) play important roles in environmental, chemical and biological fields, but the controlled release and migration of ROS remain a major challenge. Here, a highly efficient catalyst (Cu-MIL-101(Fe)) by modifying the electronic structure was designed. The orbital hybridization achieves a deep optimization of the d-band (d band center shifted from −1.01 eV to −1.32 eV), which reduces bonding and antibonding orbitals energy levels, thus promoting release of SO4·-. More importantly, the interfacial micro-electric field (IMEF) formed by the intramolecular charge offset mediates the directional migration of SO4·- from Fe sites to Cu sites. These properties endow the catalyst with high-efficiency SO4·- generation, rapid release, directional migration and utilization, with a 4.3-fold increase in effective oxidant utilization over Fe2+ (from 17.12% to 73.54%). This study highlights a catalytic strategy for efficient ROS generation, release, migration and utilization for a wide range of potential applications including environmental remediation." @default.
- W4321439086 created "2023-02-22" @default.
- W4321439086 creator A5002869474 @default.
- W4321439086 creator A5017056133 @default.
- W4321439086 creator A5024778291 @default.
- W4321439086 creator A5036165285 @default.
- W4321439086 creator A5038603218 @default.
- W4321439086 creator A5039170939 @default.
- W4321439086 creator A5059003517 @default.
- W4321439086 date "2023-07-01" @default.
- W4321439086 modified "2023-10-15" @default.
- W4321439086 title "Revealing the synergistic mechanism of generation, release, migration and utilization of reactive oxygen species through tailoring the d-band in metal organic frameworks for water purification" @default.
- W4321439086 cites W1926950498 @default.
- W4321439086 cites W2017313611 @default.
- W4321439086 cites W2081709688 @default.
- W4321439086 cites W2317322407 @default.
- W4321439086 cites W2443933168 @default.
- W4321439086 cites W2752236451 @default.
- W4321439086 cites W2889214191 @default.
- W4321439086 cites W2896044205 @default.
- W4321439086 cites W2903655798 @default.
- W4321439086 cites W2929760230 @default.
- W4321439086 cites W2946447261 @default.
- W4321439086 cites W2953060425 @default.
- W4321439086 cites W2965536134 @default.
- W4321439086 cites W2971965055 @default.
- W4321439086 cites W2980208565 @default.
- W4321439086 cites W2988180374 @default.
- W4321439086 cites W2995688716 @default.
- W4321439086 cites W2997359723 @default.
- W4321439086 cites W3007981756 @default.
- W4321439086 cites W3008264207 @default.
- W4321439086 cites W3011056268 @default.
- W4321439086 cites W3013217720 @default.
- W4321439086 cites W3033239893 @default.
- W4321439086 cites W3039917682 @default.
- W4321439086 cites W3043063122 @default.
- W4321439086 cites W3046869552 @default.
- W4321439086 cites W3086054902 @default.
- W4321439086 cites W3093672987 @default.
- W4321439086 cites W3097547835 @default.
- W4321439086 cites W3111693568 @default.
- W4321439086 cites W3159468768 @default.
- W4321439086 cites W3168352830 @default.
- W4321439086 cites W3173354908 @default.
- W4321439086 cites W3178970872 @default.
- W4321439086 cites W3188240887 @default.
- W4321439086 cites W3196485128 @default.
- W4321439086 cites W3200083235 @default.
- W4321439086 cites W3205709750 @default.
- W4321439086 cites W4200571469 @default.
- W4321439086 cites W4205564958 @default.
- W4321439086 cites W4206394043 @default.
- W4321439086 cites W4214694688 @default.
- W4321439086 cites W4220910756 @default.
- W4321439086 cites W4223532606 @default.
- W4321439086 cites W4224244341 @default.
- W4321439086 cites W4225306937 @default.
- W4321439086 cites W4226492433 @default.
- W4321439086 cites W4237053035 @default.
- W4321439086 cites W4311086482 @default.
- W4321439086 cites W4313379943 @default.
- W4321439086 doi "https://doi.org/10.1016/j.apcatb.2023.122507" @default.
- W4321439086 hasPublicationYear "2023" @default.
- W4321439086 type Work @default.
- W4321439086 citedByCount "1" @default.
- W4321439086 crossrefType "journal-article" @default.
- W4321439086 hasAuthorship W4321439086A5002869474 @default.
- W4321439086 hasAuthorship W4321439086A5017056133 @default.
- W4321439086 hasAuthorship W4321439086A5024778291 @default.
- W4321439086 hasAuthorship W4321439086A5036165285 @default.
- W4321439086 hasAuthorship W4321439086A5038603218 @default.
- W4321439086 hasAuthorship W4321439086A5039170939 @default.
- W4321439086 hasAuthorship W4321439086A5059003517 @default.
- W4321439086 hasConcept C121332964 @default.
- W4321439086 hasConcept C127413603 @default.
- W4321439086 hasConcept C135473242 @default.
- W4321439086 hasConcept C147120987 @default.
- W4321439086 hasConcept C147789679 @default.
- W4321439086 hasConcept C161790260 @default.
- W4321439086 hasConcept C171250308 @default.
- W4321439086 hasConcept C17525397 @default.
- W4321439086 hasConcept C178790620 @default.
- W4321439086 hasConcept C185592680 @default.
- W4321439086 hasConcept C189394030 @default.
- W4321439086 hasConcept C192562407 @default.
- W4321439086 hasConcept C42360764 @default.
- W4321439086 hasConcept C48349386 @default.
- W4321439086 hasConcept C52859227 @default.
- W4321439086 hasConcept C540031477 @default.
- W4321439086 hasConcept C55493867 @default.
- W4321439086 hasConcept C62520636 @default.
- W4321439086 hasConcept C71240020 @default.
- W4321439086 hasConcept C75079739 @default.
- W4321439086 hasConcept C95269574 @default.
- W4321439086 hasConceptScore W4321439086C121332964 @default.
- W4321439086 hasConceptScore W4321439086C127413603 @default.
- W4321439086 hasConceptScore W4321439086C135473242 @default.