Matches in SemOpenAlex for { <https://semopenalex.org/work/W4321443811> ?p ?o ?g. }
- W4321443811 abstract "The 2π electron 1,3-dipole boradigermaallyl, valence-isoelectronic to an allyl cation, is synthesized from a bis(germylene). It reacts with benzene at room temperature by insertion of a boron atom into the benzene ring. Computational investigation of the mechanism shows the boradigermaallyl reacting with a benzene molecule in a concerted (4+3) or [π4s+π2s] cycloaddition reaction. Thus, the boradigermaallyl acts as a highly reactive dienophile in this cycloaddition reaction with nonactivated benzene as diene unit. This type of reactivity provides a novel platform for ligand assisted borylene insertion chemistry." @default.
- W4321443811 created "2023-02-22" @default.
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- W4321443811 date "2023-03-24" @default.
- W4321443811 modified "2023-10-01" @default.
- W4321443811 title "Boradigermaallyl: (4+3) Cycloaddition‐Initiated Boron Insertion into Benzene" @default.
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- W4321443811 doi "https://doi.org/10.1002/anie.202301593" @default.
- W4321443811 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36807732" @default.
- W4321443811 hasPublicationYear "2023" @default.
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