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- W4321501459 abstract "Abstract A T‐shaped Pt 0 complex with a diphosphine‐borane (DPB) ligand was prepared. The Pt→B interaction enhances the electrophilicity of the metal and triggers the addition of Lewis bases to give the corresponding tetracoordinate complexes. For the first time, anionic Pt 0 complexes are isolated and structurally authenticated. X‐ray diffraction analyses show the anionic complexes [(DPB)PtX] − (X=CN, Cl, Br, I) to be square‐planar. The d 10 configuration and Pt 0 oxidation state of the metal were unambiguously established by X‐ray photoelectron spectroscopy and DFT calculations. The coordination of Lewis acids as Z‐type ligands is a powerful mean to stabilize elusive electron‐rich metal complexes and achieve uncommon geometry." @default.
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- W4321501459 date "2023-03-10" @default.
- W4321501459 modified "2023-10-14" @default.
- W4321501459 title "Square‐Planar Anionic Pt<sup>0</sup> Complexes" @default.
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- W4321501459 doi "https://doi.org/10.1002/ange.202301509" @default.
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