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- W4321789382 abstract "Abstract An enantioselective desymmetrization of curcumins with 3‐olefinic oxindoles involving a cascade double‐Michael addition strategy provides direct access to spirocyclohexanone‐oxindoles with complete regio‐ and diastereoselectivities and excellent enantioselectivities, besides good to excellent yields. The products possess three contiguous chiral centers and multiple reactive functionalities. The observed selectivities were rationalized by transitions state energy calculations at B3LYP//6‐31g(d) level of DFT." @default.
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- W4321789382 date "2023-03-23" @default.
- W4321789382 modified "2023-10-12" @default.
- W4321789382 title "Enantioselective Desymmetrization of Curcumins with 3‐Olefinic Oxindoles for the Synthesis of Spirocyclohexanoneoxindoles" @default.
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- W4321789382 doi "https://doi.org/10.1002/ejoc.202300069" @default.
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