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• W4322007977 abstract "The employment of combustion catalysts is an effective way to improve ammonium perchlorate (AP) decomposition performance during the combustion process of composite solid propellants. A classic half-sandwich iron carbonyl complex was proposed as the leading structure for exploring high-performance combustion catalysts, in which functionalized cyclobutadienes (Cb) tune the thermal stability and catalytic activity. The thermolysis of Fe2(CO)9 and substituted alkynes initiated [2 + 2] cyclization of alkyne triple bonds and gave η4-cyclobutadiene iron(0) tricarbonyl complexes, CbR1,R2-Fe-CO (1–6), with decent yields. A molecular structure analysis found that the conjugation of the aromatic substituents aryl, ferrocenyl (Fc), and triazinyl (Tz) finely tuned the coordination bonds around the Fe(0) center. The DSC/TG experiments found a remarkable thermal stability of CbTz,R-Fe-CO (3–6) with characteristic thermolysis temperatures (CTT) as high as 500 °C. The catalytic experiments demonstrated that the CTT of Cb-Fe-CO (2-6) overlapped with AP high-temperature decomposition (HTD). The thermal cross-coupling of HTD of AP and CTT of CbTz,Fc-Fe-CO (6) significantly augmented catalytic AP decomposition, resulting in a maximum energy release as high as 2828 J/g." @default.
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• W4322007977 date "2023-02-25" @default.
• W4322007977 modified "2023-10-01" @default.
• W4322007977 title "Triazine-Augmented Catalytic Activity of Cyclobutadiene Tricarbonyl Fe(0) Complexes for Thermal Decomposition of Ammonium Perchlorate" @default.
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• W4322007977 doi "https://doi.org/10.1021/acs.organomet.2c00622" @default.
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