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- W4322492320 abstract "Abstract Although iron is a dream candidate to substitute noble metals in photoactive complexes, realization of emissive and photoactive iron compounds is demanding due to the fast deactivation of their charge-transfer states. Emissive iron compounds are scarce and dual emission has not been observed before. Here we report the Fe III complex [Fe(ImP) 2 ][PF 6 ] (HImP = 1,1′-(1,3-phenylene)bis(3-methyl-1-imidazol-2-ylidene)), showing a Janus-type dual emission from ligand-to-metal charge transfer (LMCT)- and metal-to-ligand charge transfer (MLCT)-dominated states. This behaviour is achieved by a ligand design that combines four N -heterocyclic carbenes with two cyclometalating aryl units. The low-lying π * levels of the cyclometalating units lead to energetically accessible MLCT states that cannot evolve into LMCT states. With a lifetime of 4.6 ns, the strongly reducing and oxidizing MLCT-dominated state can initiate electron transfer reactions, which could constitute a basis for future applications of iron in photoredox catalysis." @default.
- W4322492320 created "2023-02-28" @default.
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- W4322492320 date "2023-02-27" @default.
- W4322492320 modified "2023-10-17" @default.
- W4322492320 title "Janus-type emission from a cyclometalated iron(iii) complex" @default.
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- W4322492320 doi "https://doi.org/10.1038/s41557-023-01137-w" @default.
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- W4322492320 hasPublicationYear "2023" @default.
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