Matches in SemOpenAlex for { <https://semopenalex.org/work/W4322492596> ?p ?o ?g. }
- W4322492596 endingPage "3574" @default.
- W4322492596 startingPage "3563" @default.
- W4322492596 abstract "CO hydrogenation to isobutyl alcohol is a promising route for CO transformation to high value-added products. However, the formation mechanism of isobutyl alcohol is complex, and its synthesis requires complex catalysts and harsh reaction conditions, which hinders the identification of active sites. Herein, we efficiently synthesized isobutyl alcohol under mild conditions over a simple Cu–ZrO2 catalyst by decreasing the Cu loading. The space–time yield (STY) of isobutyl alcohol using an optimal CZ-0.11 catalyst was as high as 61.3 g·Lcat–1·h–1 with a CO conversion of 19.2%, far surpassing the STY of the state-of-the-art isobutyl alcohol synthesis (44.6 g·Lcat–1·h–1) under harsh conditions. Decreasing the Cu loading increased the distribution of smaller Cu particles and clarified the structure–activity relationship of Cu–Zr interactions for isobutyl alcohol synthesis. The enhanced Cu–Zr interaction led to the formation of more electron-deficient Cu species on the CZ-0.11 catalyst, which enriched the linearly adsorbed CO on Cu, as demonstrated by in situ diffuse reflectance infrared Fourier-transform spectroscopy. Experimental and theoretical results revealed that coupling of the bicarbonate species on ZrO2 with the linearly adsorbed CO species on electron-deficient Cu clusters promoted the formation of C2 intermediates and finally produced isobutyl alcohol through rapid β-addition. These insights into the active sites for CO hydrogenation to isobutyl alcohol may guide further catalyst designs." @default.
- W4322492596 created "2023-02-28" @default.
- W4322492596 creator A5004691079 @default.
- W4322492596 creator A5021439513 @default.
- W4322492596 creator A5035701638 @default.
- W4322492596 creator A5040210712 @default.
- W4322492596 creator A5061035893 @default.
- W4322492596 creator A5061698874 @default.
- W4322492596 creator A5064504131 @default.
- W4322492596 creator A5067123324 @default.
- W4322492596 creator A5082323158 @default.
- W4322492596 creator A5089757687 @default.
- W4322492596 date "2023-02-27" @default.
- W4322492596 modified "2023-10-17" @default.
- W4322492596 title "Realizing and Revealing Complex Isobutyl Alcohol Production over a Simple Cu–ZrO<sub>2</sub> Catalyst" @default.
- W4322492596 cites W1093513066 @default.
- W4322492596 cites W116485872 @default.
- W4322492596 cites W1512103937 @default.
- W4322492596 cites W1964495448 @default.
- W4322492596 cites W1969864813 @default.
- W4322492596 cites W1990544790 @default.
- W4322492596 cites W1995991279 @default.
- W4322492596 cites W2025170616 @default.
- W4322492596 cites W2032675995 @default.
- W4322492596 cites W2041043074 @default.
- W4322492596 cites W2041217515 @default.
- W4322492596 cites W2044114776 @default.
- W4322492596 cites W2052746834 @default.
- W4322492596 cites W2054978187 @default.
- W4322492596 cites W2055100433 @default.
- W4322492596 cites W2065186997 @default.
- W4322492596 cites W2077468110 @default.
- W4322492596 cites W2129837023 @default.
- W4322492596 cites W2137267376 @default.
- W4322492596 cites W2238779886 @default.
- W4322492596 cites W2283009411 @default.
- W4322492596 cites W2324794136 @default.
- W4322492596 cites W2326809340 @default.
- W4322492596 cites W2496909608 @default.
- W4322492596 cites W2565036453 @default.
- W4322492596 cites W2579891120 @default.
- W4322492596 cites W2589296830 @default.
- W4322492596 cites W2591429458 @default.
- W4322492596 cites W2746437960 @default.
- W4322492596 cites W2781587340 @default.
- W4322492596 cites W2788637447 @default.
- W4322492596 cites W2793843996 @default.
- W4322492596 cites W2802636434 @default.
- W4322492596 cites W2808287754 @default.
- W4322492596 cites W2883390734 @default.
- W4322492596 cites W2893229243 @default.
- W4322492596 cites W2906156810 @default.
- W4322492596 cites W2939180190 @default.
- W4322492596 cites W2946404879 @default.
- W4322492596 cites W2948523450 @default.
- W4322492596 cites W2964641221 @default.
- W4322492596 cites W2990817375 @default.
- W4322492596 cites W3019037555 @default.
- W4322492596 cites W3022670261 @default.
- W4322492596 cites W3042678571 @default.
- W4322492596 cites W3048286187 @default.
- W4322492596 cites W3087691796 @default.
- W4322492596 cites W3092637008 @default.
- W4322492596 cites W3100529310 @default.
- W4322492596 cites W3101066788 @default.
- W4322492596 cites W3101552560 @default.
- W4322492596 cites W3108624877 @default.
- W4322492596 cites W3108646962 @default.
- W4322492596 cites W3109966872 @default.
- W4322492596 cites W3111998435 @default.
- W4322492596 cites W3147613640 @default.
- W4322492596 cites W3170083758 @default.
- W4322492596 cites W3180792684 @default.
- W4322492596 cites W3205665698 @default.
- W4322492596 cites W3215032004 @default.
- W4322492596 cites W4206084858 @default.
- W4322492596 cites W4214611001 @default.
- W4322492596 cites W4214943031 @default.
- W4322492596 cites W4281565401 @default.
- W4322492596 cites W4283168625 @default.
- W4322492596 cites W4295951220 @default.
- W4322492596 doi "https://doi.org/10.1021/acscatal.2c05791" @default.
- W4322492596 hasPublicationYear "2023" @default.
- W4322492596 type Work @default.
- W4322492596 citedByCount "2" @default.
- W4322492596 countsByYear W43224925962023 @default.
- W4322492596 crossrefType "journal-article" @default.
- W4322492596 hasAuthorship W4322492596A5004691079 @default.
- W4322492596 hasAuthorship W4322492596A5021439513 @default.
- W4322492596 hasAuthorship W4322492596A5035701638 @default.
- W4322492596 hasAuthorship W4322492596A5040210712 @default.
- W4322492596 hasAuthorship W4322492596A5061035893 @default.
- W4322492596 hasAuthorship W4322492596A5061698874 @default.
- W4322492596 hasAuthorship W4322492596A5064504131 @default.
- W4322492596 hasAuthorship W4322492596A5067123324 @default.
- W4322492596 hasAuthorship W4322492596A5082323158 @default.
- W4322492596 hasAuthorship W4322492596A5089757687 @default.
- W4322492596 hasConcept C118792377 @default.