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- W4322736935 abstract "Abstract In this study, the Friedel crafts alkylation of indole with α, β‐unsaturated ketones catalyzed by arene diazonium tetrafluoroborate salts is reported for the first time, and the optimal conditions of this reaction were explored. The experimental results show that the optimal conditions employed 10 mol % 2‐(2‐bromophenoxy)phenyl diazonium fluoborate ( 2 ) as a catalyst, CH 3 OH as a solvent, 60 °C as reaction temperature, and 24 h as reaction time. Under these optimized conditions, the reaction of indoles with various α,β‐unsaturated ketones can proceed smoothly to obtain aimed products ( 8 ). Yields of these reactions ranged from 60 % to 92 %. The reaction conditions are mild and the reaction operation is simple." @default.
- W4322736935 created "2023-03-03" @default.
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- W4322736935 date "2023-02-28" @default.
- W4322736935 modified "2023-10-02" @default.
- W4322736935 title "Arene Diazonium Tetrafluoroborate Salts: Novel Lewis Acid Catalysts for Friedel‐Crafts Alkylation of Indoles with α,β‐Unsaturated Ketones" @default.
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- W4322736935 doi "https://doi.org/10.1002/slct.202204860" @default.
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