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• W4322738081 abstract "Abstract The development of solid‐state proton conductors with high proton conductivity at low temperatures is crucial for the implementation of hydrogen‐based technologies for portable and automotive applications. Here, we report on the discovery of a new crystalline metal acid triphosphate, ZrH 5 (PO 4 ) 3 (ZP3), which exhibits record‐high proton conductivity of 0.5–3.1×10 −2 S cm −1 in the range 25–110 °C in anhydrous conditions. This is the highest anhydrous proton conductivity ever reported in a crystalline solid proton conductor in the range 25–110 °C. Superprotonic conductivity in ZP3 is enabled by extended defective frustrated hydrogen bond chains, where the protons are dynamically disordered over two oxygen centers. The high proton conductivity and stability in anhydrous conditions make ZP3 an excellent candidate for innovative applications in fuel cells without the need for complex water management systems, and in other energy technologies requiring fast proton transfer." @default.
• W4322738081 created "2023-03-03" @default.
• W4322738081 creator A5027407764 @default.
• W4322738081 creator A5037873198 @default.
• W4322738081 creator A5043265812 @default.
• W4322738081 creator A5049988713 @default.
• W4322738081 creator A5081683969 @default.
• W4322738081 date "2023-03-23" @default.
• W4322738081 modified "2023-09-25" @default.
• W4322738081 title "Anhydrous Superprotonic Conductivity in the Zirconium Acid Triphosphate ZrH₅(PO₄)₃**" @default.
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