FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4322757652> ?p ?o ?g. }

• W4322757652 endingPage "2320" @default.
• W4322757652 startingPage "2312" @default.
• W4322757652 abstract "Positively charged Cu sites have been confirmed to significantly promote the production of multicarbon (C2) products from an electrochemical CO2 reduction reaction (CO2RR). However, the positively charged Cu has difficulty in existing under a strong negative bias. In this work, we design a Pdδ--Cu3N catalyst containing charge-separated Pdδ--Cuδ+ atom pair that can stabilize the Cuδ+ sites. In situ characterizations and density functional theory reveal that the first reported negatively charged Pdδ- sites exhibited a superior CO binding capacity together with the adjacent Cuδ+ sites, synergistically promoting the CO dimerization process to produce C2 products. As a result, we achieve a 14-fold increase in the C2 product Faradaic efficiency (FE) on Pdδ--Cu3N, from 5.6% to 78.2%. This work provides a new strategy for synthesizing negative valence atom-pair catalysts and an atomic-level modulation approach of unstable Cuδ+ sites in the CO2RR." @default.
• W4322757652 created "2023-03-03" @default.
• W4322757652 creator A5005239842 @default.
• W4322757652 creator A5019053282 @default.
• W4322757652 creator A5027375542 @default.
• W4322757652 creator A5029786087 @default.
• W4322757652 creator A5032351385 @default.
• W4322757652 creator A5032988244 @default.
• W4322757652 creator A5035786530 @default.
• W4322757652 creator A5042841794 @default.
• W4322757652 creator A5047845842 @default.
• W4322757652 creator A5054981857 @default.
• W4322757652 creator A5061335554 @default.
• W4322757652 date "2023-03-02" @default.
• W4322757652 modified "2023-10-14" @default.
• W4322757652 title "Charge-Separated Pd^δ−–Cu^δ+ Atom Pairs Promote CO₂ Reduction to C₂" @default.
• W4322757652 cites W2000685513 @default.
• W4322757652 cites W2041726686 @default.
• W4322757652 cites W2055970997 @default.
• W4322757652 cites W2082208327 @default.
• W4322757652 cites W2153119219 @default.
• W4322757652 cites W2172129767 @default.
• W4322757652 cites W2199208506 @default.
• W4322757652 cites W2313091276 @default.
• W4322757652 cites W2315641248 @default.
• W4322757652 cites W2315653339 @default.
• W4322757652 cites W2477672706 @default.
• W4322757652 cites W2586677999 @default.
• W4322757652 cites W2594035057 @default.
• W4322757652 cites W2620431768 @default.
• W4322757652 cites W2785060548 @default.
• W4322757652 cites W2788054763 @default.
• W4322757652 cites W2803001805 @default.
• W4322757652 cites W2803607967 @default.
• W4322757652 cites W2805521597 @default.
• W4322757652 cites W2889577864 @default.
• W4322757652 cites W2894633064 @default.
• W4322757652 cites W2895982214 @default.
• W4322757652 cites W2901156170 @default.
• W4322757652 cites W2928081315 @default.
• W4322757652 cites W2930237359 @default.
• W4322757652 cites W2988615383 @default.
• W4322757652 cites W2996755838 @default.
• W4322757652 cites W3011311522 @default.
• W4322757652 cites W3017185512 @default.
• W4322757652 cites W3020045489 @default.
• W4322757652 cites W3022148156 @default.
• W4322757652 cites W3029508168 @default.
• W4322757652 cites W3033087327 @default.
• W4322757652 cites W3038859973 @default.
• W4322757652 cites W3045582120 @default.
• W4322757652 cites W3046242291 @default.
• W4322757652 cites W3097542625 @default.
• W4322757652 cites W3137254585 @default.
• W4322757652 cites W3160895661 @default.
• W4322757652 cites W3161056544 @default.
• W4322757652 cites W3167634342 @default.
• W4322757652 cites W3176632743 @default.
• W4322757652 cites W3190277579 @default.
• W4322757652 cites W3197689157 @default.
• W4322757652 cites W3198535073 @default.
• W4322757652 cites W3201689294 @default.
• W4322757652 cites W3216490564 @default.
• W4322757652 cites W4200061927 @default.
• W4322757652 cites W4210457633 @default.
• W4322757652 cites W4210489538 @default.
• W4322757652 cites W4210597164 @default.
• W4322757652 cites W4221071015 @default.
• W4322757652 cites W4224091909 @default.
• W4322757652 cites W4225131034 @default.
• W4322757652 cites W4281839694 @default.
• W4322757652 cites W4282828102 @default.
• W4322757652 cites W4289816801 @default.
• W4322757652 cites W4291795553 @default.
• W4322757652 cites W4302286489 @default.
• W4322757652 cites W4309367996 @default.
• W4322757652 cites W4311488448 @default.
• W4322757652 cites W4312065978 @default.
• W4322757652 doi "https://doi.org/10.1021/acs.nanolett.2c05112" @default.
• W4322757652 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36861218" @default.
• W4322757652 hasPublicationYear "2023" @default.
• W4322757652 type Work @default.
• W4322757652 citedByCount "7" @default.
• W4322757652 countsByYear W43227576522023 @default.
• W4322757652 crossrefType "journal-article" @default.
• W4322757652 hasAuthorship W4322757652A5005239842 @default.
• W4322757652 hasAuthorship W4322757652A5019053282 @default.
• W4322757652 hasAuthorship W4322757652A5027375542 @default.
• W4322757652 hasAuthorship W4322757652A5029786087 @default.
• W4322757652 hasAuthorship W4322757652A5032351385 @default.
• W4322757652 hasAuthorship W4322757652A5032988244 @default.
• W4322757652 hasAuthorship W4322757652A5035786530 @default.
• W4322757652 hasAuthorship W4322757652A5042841794 @default.
• W4322757652 hasAuthorship W4322757652A5047845842 @default.
• W4322757652 hasAuthorship W4322757652A5054981857 @default.
• W4322757652 hasAuthorship W4322757652A5061335554 @default.
• W4322757652 hasConcept C113196181 @default.
• W4322757652 hasConcept C130349721 @default.

• next