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• W4322757780 abstract "Solvated tungsten iodide cluster compounds are presented with the homoleptic cluster cation [(W6I8)(CH3CN)6]4+ and the heteroleptic [(W6I8)I(CH3CN)5]3+, synthesized from W6I22 in acetonitrile. Crystal structures were solved and refined on deep red single-crystals of [(W6I8)(CH3CN)6](I3)(BF4)3·H2O, [(W6I8)I(CH3CN)5](I3)2(BF4), and on a yellow single-crystal of [W6I8(CH3CN)6](BF4)4·2(CH3CN) on the basis of X-ray diffraction data. The structure of the homoleptic [(W6I8)(CH3CN)6]4+ cluster is based on the octahedral [W6I8]4+ tungsten iodide cluster core, coordinated by six apical acetonitrile ligands. The electron localisation function of [(W6I8)(CH3CN)6]4+ is calculated and solid-state photoluminescence and its temperature depedence are reported. Additionally, photoluminescence and transient absorption measurements in acetonitrile are shown. Results of the obtained data are compared to compounds containing [(M6I8)I6]2- and [(M6I8)L6]2- (M = Mo or W; L = ligand) clusters." @default.
• W4322757780 created "2023-03-03" @default.
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• W4322757780 date "2023-01-01" @default.
• W4322757780 modified "2023-10-15" @default.
• W4322757780 title "Preparation, photoluminescence and excited state properties of the homoleptic cluster cation [(W₆I₈)(CH₃CN)₆]⁴⁺" @default.
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• W4322757780 doi "https://doi.org/10.1039/d2dt04063h" @default.
• W4322757780 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36861390" @default.
• W4322757780 hasPublicationYear "2023" @default.
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