Matches in SemOpenAlex for { <https://semopenalex.org/work/W4323347907> ?p ?o ?g. }
- W4323347907 abstract "A DFT study of several L→Al(ORF)3 (L=Lewis bases) adducts allowed the identification of (iPr2S)→Al(ORF)3 1-SiPr2 as a “stable yet reactive” adduct. 1-SiPr2 was shown to act as a masked Lewis superacid able to release Al(ORF)3 under mild conditions. It could be used to abstract a ORF− ligand from (bipyMe2)Ni(ORF)2 (bipyMe2 : 6,6’-dimethyl-2,2’-dipyridyl) and generate the nickel alkoxide complex [(bipyMe2)Ni(ORF)(iPr2S)]+[(RFO)3Al−F−Al(ORF)3]− 5. Ligand exchange of iPr2S by Ph3P yielded [(bipyMe2)Ni(ORF)(PPh3)]+[(RFO)3Al−F−Al(ORF)3]− 6." @default.
- W4323347907 created "2023-03-08" @default.
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- W4323347907 date "2023-04-12" @default.
- W4323347907 modified "2023-09-30" @default.
- W4323347907 title "Taming the Lewis Superacid Al(ORF)<sub>3</sub> (RF=C(CF<sub>3</sub>)<sub>3</sub>): DFT Guided Identification of the “Stable yet Reactive” Adduct S<i>i</i>Pr<sub>2</sub>→Al(ORF)<sub>3</sub>; Its Use as ORF‐ Abstractor from a “Ni‐ORF” complex" @default.
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- W4323347907 doi "https://doi.org/10.1002/chem.202203912" @default.
- W4323347907 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36880738" @default.
- W4323347907 hasPublicationYear "2023" @default.
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