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• W4323348523 abstract "Electrochemical CO2-to-CO conversion offers an attractive and efficient route to recycle CO2 greenhouse gas. Molecular catalysts, like CoPc, are proved to be possible replacement for precious metal-based catalysts. These molecules, a combination of metal center and organic ligand molecule, may evolve into single atom structure for enhanced performance; besides, the manipulation of molecules’ behavior also plays an important role in mechanism research. Here, in this work, the structure evolution of CoPc molecules is investigated via electrochemical-induced activation process. After numbers of cyclic voltammetry scanning, CoPc molecular crystals become cracked and crumbled, meanwhile the released CoPc molecules migrate to the conductive substrate. Atomic-scale HAADF-STEM proves the migration of CoPc molecules, which is the main reason for the enhancement in CO2-to-CO performance. The as-activated CoPc exhibits a maximum FECO of 99% in an H-type cell and affords a long-term durability at 100 mA cm−2 for 29.3 h in a membrane electrode assembly reactor. Density-functional theory (DFT) calculation also demonstrates a favorable CO2 activation energy with such an activated CoPc structure. This work provides a different perspective for understanding molecular catalysts as well as a reliable and universal method for practical utilization." @default.
• W4323348523 created "2023-03-08" @default.
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• W4323348523 date "2023-03-06" @default.
• W4323348523 modified "2023-10-16" @default.
• W4323348523 title "Isolation of Highly Reactive Cobalt Phthalocyanine via Electrochemical Activation for Enhanced CO₂ Reduction Reaction" @default.
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• W4323348523 doi "https://doi.org/10.1002/smll.202207037" @default.
• W4323348523 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36879480" @default.
• W4323348523 hasPublicationYear "2023" @default.
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