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- W4323652197 abstract "Abstract Organic nitrates are broadly applied as pharmaceuticals (acting as efficient nitric oxide donor), energetic materials, building blocks in organic synthesis, etc. However, practical and direct methods to access organic nitrates efficiently are still rare, mainly due to the lack of powerful nitrooxylating reagents. Herein, we report bench‐stable and highly reactive noncyclic hypervalent iodine nitrooxylating reagents, oxybis(aryl‐λ 3 ‐iodanediyl) dinitrates (OAIDNs, 2 ), which are prepared just by using aryliodine diacetate and HNO 3 . The reagents are used to achieve a mild and operationally simple protocol to access diverse organic nitrates. By employing of 2 , zinc‐catalyzed regioselective nitrooxylation of cyclopropyl silyl ethers is realized efficiently to access the corresponding β‐nitrooxy ketones with high functional‐group tolerance. Moreover, a series of direct and catalyst‐free nitrooxylations of enolizable C−H bonds are carried out smoothly to afford the desired organic nitrates within minutes by just mixing the substrates with 2 in dichloromethane." @default.
- W4323652197 created "2023-03-10" @default.
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- W4323652197 date "2023-03-27" @default.
- W4323652197 modified "2023-09-26" @default.
- W4323652197 title "Simple and Versatile Nitrooxylation: Noncyclic Hypervalent Iodine Nitrooxylating Reagent" @default.
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- W4323652197 doi "https://doi.org/10.1002/anie.202302521" @default.
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