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• W4323667482 startingPage "2651" @default.
• W4323667482 abstract "Perovskites (PVKs) have emerged as an exciting class of semiconducting materials owing to their magnificent photophysical properties and been used in solar cells, light-emitting diodes, photodetectors, etc. The growth of multidimensional nanostructures has revealed many exciting alterations in their optoelectronic properties compared to those of their bulk counterparts. In this work, we have spotlighted the influence of quantum confinement in CsPbBr3 PVKs like the quantum dot (PQD), nanoplatelet (PNPL), and nanorod (PNR) on their charge transfer (CT) dynamics with 1,4-naphthoquinone (NPQ). The energy band alignment facilitates the transfer of both electrons and holes in the PNPL to NPQ, enhancing its CT rate, while only electron transfer in the PQD and PNR diminishes CT. The tunneling current across a metal-nanostructure-metal junction for the PNPL is observed to be higher than others. The higher exciton binding energy in the PNPL results in efficient charge transport by enhancing the mobility of the excited-state carrier and its lifetime compared to those of the PNR and PQD." @default.
• W4323667482 created "2023-03-10" @default.
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• W4323667482 date "2023-03-09" @default.
• W4323667482 modified "2023-09-27" @default.
• W4323667482 title "Deciphering the Relevance of Quantum Confinement in the Optoelectronics of CsPbBr₃ Perovskite Nanostructures" @default.
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• W4323667482 doi "https://doi.org/10.1021/acs.jpclett.3c00010" @default.
• W4323667482 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36924080" @default.
• W4323667482 hasPublicationYear "2023" @default.
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