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- W4323767572 abstract "Nanocluster photoluminescence (PL) has important practical applications and its rationalization is therefore of significant interest. Here, we report the synthesis, structure determination and photoluminescence of Au10Ag17(TPP)10(SR)6Cl5 (TPP = triphenylphosphine, SR = 3, 5-bis(trifluoromethyl)thiophenol, denoted as Au10Ag17). Au10Ag17 exhibited a low photoluminescence quantum yield (PLQY) of 2.8%, which could be increased 15-fold by removing the two terminal silver atoms to give AgxAu25-x(SR)5(TPP)10Cl22+ (x = 11-13, SR = 2-phenylethylmercaptan, abbrev. Au12Ag13). The discovery of such a PL switch constitutes an interesting opportunity to further understand the origin of fluorescence in nanoclusters." @default.
- W4323767572 created "2023-03-11" @default.
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- W4323767572 date "2023-01-01" @default.
- W4323767572 modified "2023-10-15" @default.
- W4323767572 title "Au<sub>10</sub>Ag<sub>17</sub>(TPP)<sub>10</sub>(SR)<sub>6</sub>Cl<sub>5</sub> nanocluster: structure, transformation and the origin of its photoluminescence" @default.
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- W4323767572 doi "https://doi.org/10.1039/d3cp00459g" @default.
- W4323767572 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36946196" @default.
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