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- W4323822313 abstract "(Borylmethyl)trimethylsilanes are important building blocks in organic synthesis displaying a unique reactivity. Yet, the synthesis of more advanced derivatives is limited by the advanced silicon intermediates required for their preparation. Herein, a one-pot synthesis of (borylmethyl)silanes is developed, sourced on available alkyl-, aryl-, alkoxy-, aryloxy-, and silyl-hydrosilane materials. The privileged reactivity of N-hydroxyphthalimidyl diazoacetate (NHPI-DA) in Si–H insertion and α-silyl redox-active esters in different decarboxylative borylation reactions are scrutinized." @default.
- W4323822313 created "2023-03-11" @default.
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- W4323822313 date "2023-03-10" @default.
- W4323822313 modified "2023-10-18" @default.
- W4323822313 title "Modular Synthesis of (Borylmethyl)silanes through Orthogonal Functionalization of a Carbon Atom" @default.
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- W4323822313 doi "https://doi.org/10.1021/acs.orglett.3c00474" @default.
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