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- W4323920937 abstract "Abstract Indenone azines, in which the exocyclic C=C bond in dibenzopentafulvalene is replaced by an azine moiety (C=N−N=C), have been synthesized as novel electron‐accepting π‐conjugated scaffolds. Structural modulation at the 7,7′‐positions of indenone azines enabled stereoselective syntheses of diastereomers in which the configurations of the two C=N bonds are E,E or Z,Z . X‐ray crystallographic analyses revealed that all the indenone azines exhibit high coplanarity in contrast to the twisted frameworks of dibenzopentafulvalene derivatives, resulting in the formation of densely π‐stacked structures. Electrochemical measurements and quantum chemical calculations revealed the electron‐accepting character of indenone azines comparable to isoindigo dyes. In particular, the intramolecular hydrogen bonds of 7,7′‐dihydroxy‐substituted derivatives impart enhanced electron‐accepting character and significantly red‐shifted photoabsorption. This study demonstrates that indenone azines represent a promising candidate as electron‐accepting building blocks for optoelectronic materials." @default.
- W4323920937 created "2023-03-12" @default.
- W4323920937 creator A5000037090 @default.
- W4323920937 creator A5075973263 @default.
- W4323920937 creator A5089337574 @default.
- W4323920937 date "2023-04-03" @default.
- W4323920937 modified "2023-10-11" @default.
- W4323920937 title "Stereoselective Synthesis and Characterization of Indenone Azine‐Based Electron‐Accepting π‐Conjugated Systems" @default.
- W4323920937 cites W1964056216 @default.
- W4323920937 cites W1967716441 @default.
- W4323920937 cites W1971758471 @default.
- W4323920937 cites W1982027396 @default.
- W4323920937 cites W1984434003 @default.
- W4323920937 cites W1985498609 @default.
- W4323920937 cites W1993936793 @default.
- W4323920937 cites W1997855068 @default.
- W4323920937 cites W2006684601 @default.
- W4323920937 cites W2011348505 @default.
- W4323920937 cites W2014517777 @default.
- W4323920937 cites W2016088184 @default.
- W4323920937 cites W2025344514 @default.
- W4323920937 cites W2028494199 @default.
- W4323920937 cites W2035515373 @default.
- W4323920937 cites W2040461435 @default.
- W4323920937 cites W2041720184 @default.
- W4323920937 cites W2042324637 @default.
- W4323920937 cites W2043020327 @default.
- W4323920937 cites W2047546871 @default.
- W4323920937 cites W2049286900 @default.
- W4323920937 cites W2051214633 @default.
- W4323920937 cites W2052230185 @default.
- W4323920937 cites W2057753783 @default.
- W4323920937 cites W2059182153 @default.
- W4323920937 cites W2059668887 @default.
- W4323920937 cites W2066260730 @default.
- W4323920937 cites W2081440341 @default.
- W4323920937 cites W2082686304 @default.
- W4323920937 cites W2086940279 @default.
- W4323920937 cites W2088654035 @default.
- W4323920937 cites W2088865378 @default.
- W4323920937 cites W2103221532 @default.
- W4323920937 cites W2116764827 @default.
- W4323920937 cites W2120626517 @default.
- W4323920937 cites W2131407064 @default.
- W4323920937 cites W2147304506 @default.
- W4323920937 cites W2150142090 @default.
- W4323920937 cites W2170021353 @default.
- W4323920937 cites W2191794549 @default.
- W4323920937 cites W2200979298 @default.
- W4323920937 cites W2237268359 @default.
- W4323920937 cites W2262193673 @default.
- W4323920937 cites W2275474525 @default.
- W4323920937 cites W2314416268 @default.
- W4323920937 cites W2317898558 @default.
- W4323920937 cites W2323584865 @default.
- W4323920937 cites W2327760352 @default.
- W4323920937 cites W2346635112 @default.
- W4323920937 cites W2384540119 @default.
- W4323920937 cites W2403634190 @default.
- W4323920937 cites W2516416574 @default.
- W4323920937 cites W2553969093 @default.
- W4323920937 cites W2775964141 @default.
- W4323920937 cites W2785534485 @default.
- W4323920937 cites W2786600397 @default.
- W4323920937 cites W2792016222 @default.
- W4323920937 cites W2885513326 @default.
- W4323920937 cites W2890363564 @default.
- W4323920937 cites W2900942893 @default.
- W4323920937 cites W2902428772 @default.
- W4323920937 cites W2910929063 @default.
- W4323920937 cites W2933478408 @default.
- W4323920937 cites W2950152876 @default.
- W4323920937 cites W2951460709 @default.
- W4323920937 cites W2969376678 @default.
- W4323920937 cites W2977599311 @default.
- W4323920937 cites W3011034258 @default.
- W4323920937 cites W3022321780 @default.
- W4323920937 cites W3153026511 @default.
- W4323920937 cites W3156969670 @default.
- W4323920937 cites W3164024513 @default.
- W4323920937 cites W3183720835 @default.
- W4323920937 cites W3206880499 @default.
- W4323920937 cites W3216850667 @default.
- W4323920937 cites W4211000478 @default.
- W4323920937 cites W4231395857 @default.
- W4323920937 cites W4234356102 @default.
- W4323920937 cites W4238043123 @default.
- W4323920937 cites W4238372088 @default.
- W4323920937 cites W4239186989 @default.
- W4323920937 cites W4242285046 @default.
- W4323920937 cites W4245622281 @default.
- W4323920937 cites W4247477017 @default.
- W4323920937 cites W4248453103 @default.
- W4323920937 cites W4250119131 @default.
- W4323920937 cites W4255184607 @default.
- W4323920937 cites W4281491899 @default.
- W4323920937 cites W4283827564 @default.
- W4323920937 cites W4284689971 @default.
- W4323920937 cites W4285194260 @default.
- W4323920937 doi "https://doi.org/10.1002/chem.202300181" @default.