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- W4324018081 abstract "CuX/TiO2 adsorbents with CuO as the active component were prepared via a simple impregnation method for efficient purification of phosphine (PH3) under the conditions of low temperatures (90 °C) and low oxygen concentration (1%). The PH3 breakthrough capacity of optimal adsorbent (Cu30/TiO2) is 136.2 mg(PH3)·gsorbent-1, and the excellent dephosphorization performance is mainly attributed to its abundant sur face-active oxygen and alkaline sites, large specific surface area, and strong interaction between CuO and the support TiO2. Surprisingly, CuO is converted to Cu3P after the dephosphorization by CuX/TiO2. Since Cu3P is a P-type semiconductor with high added value, the deactivated adsorbent (Cu3P/TiO2) is an efficient heterostructure photocatalyst for photocatalytic removal of Hg0 (gas) with the Hg0 removal performance of 92.64% under visible light. This study provides a feasible strategy for the efficient removal and resource conversion of PH3 under low-temperature conditions and the alleviation of the environmental risk of secondary pollution." @default.
- W4324018081 created "2023-03-14" @default.
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- W4324018081 date "2023-03-13" @default.
- W4324018081 modified "2023-10-13" @default.
- W4324018081 title "Two Birds with One Stone: Copper-Based Adsorbents Used for Photocatalytic Oxidation of Hg<sup>0</sup> (Gas) after Removal of PH<sub>3</sub>" @default.
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- W4324018081 doi "https://doi.org/10.1021/acs.est.3c00065" @default.
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