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- W4324056565 abstract "We found an effective catalytic consortium capable of converting glucose to 5-hydroxymethylfurfural (HMF) in high yields (50%). The reaction consists of a consortium of a Lewis acid (NbCl5) and a Brønsted acid (p-sulfonic acid calix[4]arene (CX4SO3H)), in a microwave-assisted reactor and in a biphasic system. The best result for the conversion of glucose to HMF (yield of 50%) was obtained with CX4SO3H/NbCl5 (5 wt%/7.5 wt%), using water/NaCl and MIBK (1:3), at 150 °C, for 17.5 min. The consortium catalyst recycling was tested, allowing its reuse for up to seven times, while maintaining the HMF yield constant. Additionally, it proposed a catalytic cycle by converting glucose to HMF, highlighting the following two key points: the isomerization of glucose into fructose, in the presence of Lewis acid (NbCl5), and the conversion of fructose into HMF, in the presence of CX4SO3H/NbCl5. A mechanism for the conversion of glucose to HMF was proposed and validated." @default.
- W4324056565 created "2023-03-14" @default.
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- W4324056565 date "2023-03-12" @default.
- W4324056565 modified "2023-09-26" @default.
- W4324056565 title "Conversion of Glucose to 5-Hydroxymethylfurfural Using Consortium Catalyst in a Biphasic System and Mechanistic Insights" @default.
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- W4324056565 doi "https://doi.org/10.3390/catal13030574" @default.
- W4324056565 hasPublicationYear "2023" @default.
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