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• W4324101786 endingPage "136778" @default.
• W4324101786 startingPage "136778" @default.
• W4324101786 abstract "This paper proposes an electrochemical chloride extraction (ECE) model for cement-based materials that considers coupled multi-ion transport, adsorption and dissolution. Then ECE tests were designed and conducted to validate the proposed ECE model. Based on the proposed ECE model, parametric studies were conducted. Parametric studies show that the chloride binding capacity of cement pastes depends heavily on the contents of aluminate ferrite monosulfate (AFm) and alumina ferrite tri-sulfate (AFt). Moreover, the content compositions of free, absorbed and chemically-bound chloride ions vary with the types of chloride salts, i.e., the cations in the chloride salts. Moreover, temperatures within the range between 5 °C and 40 °C pose negligible influences on the ECE process. Current densities and durations are the most influential factors affecting the ECE process, which are thus the main parameters to be determined for the design of ECE. In addition, the chloride ion content distributions are bell curves during the ECE process and peaks exist within the concrete cover. Therefore, it is recommended to adopt three chloride ion contents as controlling indexes for the ECE process, i.e., 1) the chloride ion content at the surface of steel bars, 2) the average chloride ion content within the concrete cover and 3) the peak chloride ion content within the concrete cover." @default.
• W4324101786 created "2023-03-14" @default.
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• W4324101786 date "2023-05-01" @default.
• W4324101786 modified "2023-09-27" @default.
• W4324101786 title "Modeling electrochemical chloride extraction process in cement-based materials considering coupled multi-ion transports and thermodynamic equilibriums" @default.
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• W4324101786 doi "https://doi.org/10.1016/j.jclepro.2023.136778" @default.
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