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• W4324132690 abstract "Frustrated Lewis pairs (FLPs), discovered in the last few decades for homogeneous catalysts and in the last few years also for heterogeneous catalysts, are stimulating the scientific community's interest for their potential in small-molecule activation. Nevertheless, how an FLP activates stable molecules such as CO2 is still undefined. Through a careful spectroscopic study, we here report the formation of FLPs over a highly defective CeO2 sample prepared by microwave-assisted synthesis. Carbon dioxide activation over FLP is shown to occur through a bidentate carbonate bridging the FLP and implying a Ce3+-to-CO2 charge transfer, thus enhancing its activation. Carbon dioxide reaction with methanol to form monomethylcarbonate is here employed to demonstrate active roles of FLP and, eventually, to propose a reaction mechanism clarifying the role of Ce3+ and oxygen vacancies." @default.
• W4324132690 created "2023-03-15" @default.
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• W4324132690 date "2023-03-14" @default.
• W4324132690 modified "2023-09-30" @default.
• W4324132690 title "CeO₂ Frustrated Lewis Pairs Improving CO₂ and CH₃OH Conversion to Monomethylcarbonate" @default.
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• W4324132690 doi "https://doi.org/10.1021/acsami.2c22122" @default.
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