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- W4324135672 abstract "We investigate the postulate that hydrogen pressure influences the furfural hydrogenation selectivity on palladium to form decarbonylation products at low hydrogen pressures, but 2-methyl furan at higher pressures. This change is caused by co-adsorbed hydrogen changing the orientation of adsorbed furfural; low hydrogen coverages favor flat-lying furfural, higher coverages form tilted species. This was tested for hydrogenation of furfural on a Pd(1 1 1) single crystal. The product distribution agreed with the postulate, with 100% selectivity to furan and tetrahydrofuran for low hydrogen pressures, with 2-methyl furan increasing with hydrogen pressure. The origin of the effect is explored using reflection–absorption infrared spectroscopy. This showed that co-adsorbed hydrogen influenced the orientation in a way predicted by theory. It was also found that other co-adsorbates displayed similar effects implying that a range of molecules in the reaction mixture could have significant effects on the furfural selectivity." @default.
- W4324135672 created "2023-03-15" @default.
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- W4324135672 date "2023-05-01" @default.
- W4324135672 modified "2023-10-05" @default.
- W4324135672 title "Metrics of performance relevant in methanol-to-hydrocarbons catalysis" @default.
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- W4324135672 doi "https://doi.org/10.1016/j.jcat.2023.03.022" @default.
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