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• W4324322182 abstract "Ti-catalyzed oxidative alkyne carboamination with alkenes and azo compounds can yield either α,β-unsaturated imines or cyclopropyl imines through a common azatitanacyclohexene intermediate. Herein, we report the synthesis of a model azatitanacyclohexene complex (3) through the ring-opening of a cyclopropyl imine with Cp2Ti(BTMSA) (BTMSA = bis(trimethylsilyl)acetylene). 3 readily undergoes thermal or reductant-catalyzed ring contraction to an azatitanacyclopentene (4), analogous to the proposed mechanism for forming α,β-unsaturated imines in the catalytic reaction. A cyclopropyl imine or an α,β-unsaturated imine could be liberated via the oxidation of 3 or 4 with azobenzene, respectively, further implicating the role of these metallacycles in the Ti-catalyzed carboamination reaction." @default.
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• W4324322182 date "2023-03-15" @default.
• W4324322182 modified "2023-10-16" @default.
• W4324322182 title "Cp₂Ti(II) Mediated Rearrangement of Cyclopropyl Imines" @default.
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• W4324322182 doi "https://doi.org/10.1021/acs.organomet.3c00032" @default.
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