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• W4324334045 abstract "Alloying plays an important role in controlling the phase stability, mechanical properties, and deformation behavior of ordered intermetallic compounds. In this study, the effects of 3d, 4d, and 5d transition elements on site preference, elastic properties, ideal shear strength, and planar fault energies of L12 Co–Ti-based alloys were systematically investigated by using first-principles calculations. The calculated transfer energy and formation enthalpy indicate that Sc, V, Cr, Y, Zr, Nb, Mo, W, Hf, Ta, and W tend to occupy the Ti site, which reduce the structural stability of L12-Co3Ti. The elastic moduli and ideal shear strength of L12-Co3(Ti,M) increase with average electron density. The electron localization function (ELF) analysis reveals that the Co–M bonds have a stronger covalent character than the Co–Ti bond, which plays an important role in the strengthening of the alloys. The ratio of superlattice intrinsic stacking fault (SISF) to anti-phase boundary (APB) energy of L12-Co3(Ti,M) decreases with increasing atomic number of alloying elements in each period in the range of studied elements, which tends to change the deformation mode from the APB-favored to SISF-favored ones. The APB anisotropy ratio of L12-Co3(Ti,M) decreases with increasing atomic number of alloying elements in each period, which enhances the yield strength anomaly. This study not only sheds insight into the fundamental understanding of phase stability and mechanical behavior of multicomponent L12 compounds, but also provides useful guidelines for designing novel L12-stregnthened Co-based superalloys with superior mechanical properties." @default.
• W4324334045 created "2023-03-16" @default.
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• W4324334045 date "2023-05-01" @default.
• W4324334045 modified "2023-10-16" @default.
• W4324334045 title "Alloying effects on site preference, mechanical properties, and deformation behavior of L12 Co–Ti-based alloys" @default.
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• W4324334045 doi "https://doi.org/10.1016/j.jmrt.2023.03.099" @default.
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