FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4324339611> ?p ?o ?g. }

• W4324339611 endingPage "135361" @default.
• W4324339611 startingPage "135361" @default.
• W4324339611 abstract "Interesting results have been found for new compounds derived from oxo-pyrimidine to protect of mild steel (MS) in 1 M hydrochloric acid. These the compounds are 1-(5-(4-Methoxy-benzoyl)-4-(4‑methoxy-phenyl)-2-oxo-2H-pyrimidin-1-yl]-(4‑methoxy-phenyl)-urea (MMOM) and 1-(5-(4‑methoxy-benzoyl)-4-(4‑methoxy-phenyl)-2-oxo-2H-pyrimidin-1-yl)-3-(4-methlyphenyl)-thiourea (MMOPM). In this study, the impact of immersion time on inhibitor effectiveness was also investigated. Both substances function as mixed-type inhibitors, according to the electrochemical data. At 5 × 10−4 M and a 72-hour immersion duration, MMOM is more effective than MMOPM (98.42% vs. 94.49%). The Langmuir isotherm system provided the best match for both compounds, with chemisorption as the kind of adsorption. According to the findings of surface characterisation, both chemicals may be adsorbed on mild steel surfaces to reduce corrosion. Inhibitor simulations using density functional theory revealed that the protonated state is more reactive than the neutral state and coincides with experimental findings. The outcomes demonstrated that both compounds may be utilised as new mild steel corrosion inhibitors in harsh conditions and long-term immersion. The theoretical study, based on quantum chemical calculations of the compounds, performed by the DFT/BP86 method with a 6–311G(d,p) basis set by using Gaussian 09, Revision A.02 program, were also included to support experimental results. The various quantum chemical parameters such as EHOMO, ELUMO, chemical hardness and chemical softness, electronegativity of the investigated molecules were calculated, and their inhibition efficiency were discussed. The outcomes demonstrated that both compounds may be utilised as new mild steel corrosion inhibitors in harsh conditions and long-term immersion." @default.
• W4324339611 created "2023-03-16" @default.
• W4324339611 creator A5000617535 @default.
• W4324339611 creator A5001040550 @default.
• W4324339611 creator A5011690424 @default.
• W4324339611 creator A5016740276 @default.
• W4324339611 creator A5027404156 @default.
• W4324339611 creator A5040870565 @default.
• W4324339611 creator A5091152655 @default.
• W4324339611 date "2023-07-01" @default.
• W4324339611 modified "2023-10-18" @default.
• W4324339611 title "Corrosion inhibition of mild steel in acidic media using new oxo-pyrimidine derivatives: Experimental and theoretical insights" @default.
• W4324339611 cites W1228944301 @default.
• W4324339611 cites W1874196965 @default.
• W4324339611 cites W1898285119 @default.
• W4324339611 cites W1965173894 @default.
• W4324339611 cites W1974741171 @default.
• W4324339611 cites W1978005206 @default.
• W4324339611 cites W1985562733 @default.
• W4324339611 cites W1988078840 @default.
• W4324339611 cites W1988274178 @default.
• W4324339611 cites W1989750184 @default.
• W4324339611 cites W1994941357 @default.
• W4324339611 cites W1999776035 @default.
• W4324339611 cites W2001940015 @default.
• W4324339611 cites W2009212725 @default.
• W4324339611 cites W2015293016 @default.
• W4324339611 cites W2023567383 @default.
• W4324339611 cites W2026932304 @default.
• W4324339611 cites W2031143381 @default.
• W4324339611 cites W2031890789 @default.
• W4324339611 cites W2044685703 @default.
• W4324339611 cites W2047188818 @default.
• W4324339611 cites W2049070753 @default.
• W4324339611 cites W2049259620 @default.
• W4324339611 cites W2053794685 @default.
• W4324339611 cites W2056457760 @default.
• W4324339611 cites W2064957563 @default.
• W4324339611 cites W2065600184 @default.
• W4324339611 cites W2068242529 @default.
• W4324339611 cites W2073878574 @default.
• W4324339611 cites W2074694348 @default.
• W4324339611 cites W2074719032 @default.
• W4324339611 cites W2079788390 @default.
• W4324339611 cites W2082984671 @default.
• W4324339611 cites W2098484748 @default.
• W4324339611 cites W2130751622 @default.
• W4324339611 cites W2132151219 @default.
• W4324339611 cites W2139600112 @default.
• W4324339611 cites W2165840067 @default.
• W4324339611 cites W2169927586 @default.
• W4324339611 cites W2280849403 @default.
• W4324339611 cites W2309204113 @default.
• W4324339611 cites W2327342345 @default.
• W4324339611 cites W2331827140 @default.
• W4324339611 cites W2401767950 @default.
• W4324339611 cites W2413090485 @default.
• W4324339611 cites W2432694422 @default.
• W4324339611 cites W2471758328 @default.
• W4324339611 cites W2509468937 @default.
• W4324339611 cites W2514860175 @default.
• W4324339611 cites W2554361758 @default.
• W4324339611 cites W2590098501 @default.
• W4324339611 cites W2592354780 @default.
• W4324339611 cites W2600530607 @default.
• W4324339611 cites W2609911228 @default.
• W4324339611 cites W2765459118 @default.
• W4324339611 cites W2783494010 @default.
• W4324339611 cites W2790921300 @default.
• W4324339611 cites W2791807313 @default.
• W4324339611 cites W2794278486 @default.
• W4324339611 cites W2805752666 @default.
• W4324339611 cites W2805965873 @default.
• W4324339611 cites W2806764130 @default.
• W4324339611 cites W2825184923 @default.
• W4324339611 cites W2883842940 @default.
• W4324339611 cites W2884263764 @default.
• W4324339611 cites W2894370645 @default.
• W4324339611 cites W2898834147 @default.
• W4324339611 cites W2911363630 @default.
• W4324339611 cites W2912217394 @default.
• W4324339611 cites W2936482457 @default.
• W4324339611 cites W2965147724 @default.
• W4324339611 cites W2969199949 @default.
• W4324339611 cites W2978600912 @default.
• W4324339611 cites W2983467589 @default.
• W4324339611 cites W2988038063 @default.
• W4324339611 cites W2998064803 @default.
• W4324339611 cites W3003259055 @default.
• W4324339611 cites W3009796124 @default.
• W4324339611 cites W3010649765 @default.
• W4324339611 cites W3013590276 @default.
• W4324339611 cites W3015995901 @default.
• W4324339611 cites W3016359912 @default.
• W4324339611 cites W3019272839 @default.
• W4324339611 cites W3021861168 @default.
• W4324339611 cites W3025390077 @default.
• W4324339611 cites W3030729364 @default.

• next