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- W4324352308 abstract "The C4F7N/CO2/O2 gas mixture received a great deal of attention for its potential use in eco-friendly gas-insulated equipment (GIE). The evaluation of the compatibility between C4F7N/CO2/O2 and sealing rubber is necessary and significant considering the high working pressure (0.14–0.6 MPa) of GIE. Herein, we explored the compatibility between C4F7N/CO2/O2 and fluororubber (FKM) and nitrile butadiene rubber (NBR) for the first time by analyzing the gas components, rubber morphology, elemental composition, and mechanical properties. The interaction mechanism of the gas–rubber interface was further investigated based on the density functional theory. We found that C4F7N/CO2/O2 is compatible with FKM and NBR at 85 °C, while the surface morphology changed at 100 °C, with white granular and agglomerated lumps appearing on FKM and multi-layer flakes being generated on NBR. The accumulation of the fluorine element occurred, and the compressive mechanical properties of NBR deteriorated after the gas–solid rubber interaction. Overall, the compatibility between FKM and C4F7N/CO2/O2 is superior, which could be employed as the sealing material for C4F7N-based GIE." @default.
- W4324352308 created "2023-03-16" @default.
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- W4324352308 date "2023-03-15" @default.
- W4324352308 modified "2023-10-14" @default.
- W4324352308 title "Compatibility and Interaction Mechanism between the C<sub>4</sub>F<sub>7</sub>N/CO<sub>2</sub>/O<sub>2</sub> Gas Mixture and FKM and NBR" @default.
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- W4324352308 doi "https://doi.org/10.1021/acsomega.3c00195" @default.
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