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• W4327568845 startingPage "2784" @default.
• W4327568845 abstract "Radiation chemistry of hydrated metal ions plays a significant role in the field of nuclear energy, especially regarding water radiolysis in coolant water in nuclear reactors. This work reports new experimental data on the reactivity of Ni2+/+ species under critical conditions of temperature and pressure. The reaction rates of hydrated nickel ions with water radiolysis products (e-aq, •OH, H, and H2O2) have been investigated for a 25-300 °C temperature range and 200 bar pressure using electron pulse radiolysis/transient absorption. Extensive experiments with the Ni2+/+ species in various salts and pH up to 300 °C were performed. Kinetic decay traces of short-lived monovalent nickel ions were fitted to extract the rate constants versus temperature up to 300 °C. A blue shift of the absorption spectrum of the monovalent nickel ion with increasing temperature was demonstrated, which may indicate a change in the average coordination number. The Arrhenius parameters for the reactions of Ni2+ with e-aq and Ni+ with •OH, H, and H2O2 were obtained. All measured rate constants increased with temperature and followed Arrhenius behavior." @default.
• W4327568845 created "2023-03-17" @default.
• W4327568845 creator A5009529534 @default.
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• W4327568845 date "2023-03-16" @default.
• W4327568845 modified "2023-09-27" @default.
• W4327568845 title "Reactions of Nickel Ions in Water Radiolysis up to 300 °C" @default.
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• W4327568845 doi "https://doi.org/10.1021/acs.jpcb.3c00046" @default.
• W4327568845 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36926873" @default.
• W4327568845 hasPublicationYear "2023" @default.
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